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Rate
Amoiunt of reaction per unit time
Molecules must
Collide with enough KE to react
Collision model
Must have enough energy to react
Activation energy
Min energy to react
Actrivated complex
Unsatbel momintary peak of energy
Factors that effect rate
Temp, catalyst, surface area, concintration
Catalyst
Speeds up reaction
enzyme
Catalyzes biological reactions
Inhibitor
slows or stops reaction
Elementary reaction
1 step reaction
Elementary reaction product
Intermediate
Reaction mechanism
Series of elementary reactions leads to overall reaction
Reversable reaction
Conversion of reactants to products and the conversion happen simolutaniously
Doubble arrow
Reaction reversable
Le chatelier principle
stress applied to system changes to relive stress
concintration
Addign more reactant produced more product
Temp
Increasign causes shirt to direction of heat
pressure
Chnages in pressure will only effect gas
Added to system
Away
Removeed from system
tward dremovced component
Keq
Equilibrium constant
KEq expression
Product/Reactant
2nd law of thermodynamics
any spontaneous process of disorder of universe
Keq 1>
reactants favored
Keq 1<
Productgs favored
Keq 1
Equal
Favorable reaction
spontanous reaction
enthropy
measure of order and disorder within a system
Law of disorder
Natural tendency for things to be mess y
Decrease enthropy favores
Non spontanous
High enthropy favores
spontaneous
Temp in enthropy
Increasein energy follows increase in temp
Crushing
Increases enthropy
Change of state
solid to liquid enthropy higher
Enthropt increases
when more products
Spontaions reactions
Natrurally
Nonspontanious
neeeds work
+S and -H
Alwayd spontaneouus
-S and +H
NEVER spontanipous
free energy
energy able to do work