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Electrons flow from
Anode to cathode
What does the salt bridge in galvanic cells do
Keep solutions electrically neutral
Metal electrodes gain electrons at
cathode
What is true for a reaction witha negative delta H
Exothermic
How many electrons are involved in the following acidic redox reaction. ClO3¯ + SO2 ---> SO42¯ + Cl¯
6
What is the sum of the reactant coefficients in an acidic redox reaction. MnO4¯ + CH3OH ---> HCOOH + Mn2+
31
What is the correct electron configuration for the bromide ion Br-
[Ar] 4s23d104p6
What is the empirical formula of a compound composed of 50.05% sulfur and 49.95 oxygen?
SO2
A compound is found to contain 31.42 % sulfur, 31.35 % oxygen, and 37.23 % fluorine by weight. What is the empirical formula for this compound?
SO2F2
A compound was found to contain 24.74% (by mass) potassium, 34.76% manganese, and 40.50% oxygen. Determine the empirical formula.
KMnO4
What is the highest value of pressure
780 mmHg
How many kPa in an atm
101,325
How many torr in an atm
760
How many mmHg in an atm
760
If the pressure at equilibrium was more than the initial pressure, what can be said about the reaction quotient and direction of reaction as the reaction progressed towards equilibrium. N2(g) + 3 H2(g) → 2 NH3(g)
Qc>Kc, backward reaction
Qc<Kc
Ratio of products to reactants is less than at equilibrium
What direction must a reaction go for pressure to increase
Side with more moles of gas
Quantity of acid or base delivered is
volume of titrant added * titrant concentration
How many mole sof oxygen are in 190 grams of KNO3 at a temperature of 28 C
5.7
A sample of glucose (C₆H₁₂O₆) weighs 90 grams. If it is heated to 45 °C, how many moles of carbon atoms does it contain?
3 moles
How many moles of oxygen atoms are present in 82 grams of calcium nitrate, Ca(NO₃)₂, at room temperature?
3 moles
A lewis acid is
an electron acceptor
A lewis base is
an electron donor
A proton acceptor
Brosted-Lowry base
A proton donor
Bronsted-Lowry acid
In a fission reaction, uranium-235 is bombarded with a neutron and decays into two main radioactive fragments and 3 neutrons as depicted in the following reaction: 235U+ 1n→ 141Ba+X+31n
92Kr
Arrhenius Base
H+ producer
Arrhenius Acid
OH- producer
Strong Acids
I brought clean nitrate so accept
I brought clean nitrate so accept
HI, HBr, HCl, HNO3, HSO4
Never keep calcium bagged bro
NaOH, KOH, Ca(OH)2, BaOH
Strong bases
Never keep calcium bagged bro
Soluble salts
ABC’S GANG
ABC’S GANG
Ammonium, bicarbonate, chlorate, sulfate, group 1 metals, acetate, nitrate, group 17
Insoluble Salts
PMS HICCP
PMS HICCP
Pb2+, mercury, silver, hydroxide, carbonate, chromate, phosphate
Boyle’s Law
volume is inversely proportional to pressure
Charles law
volume is directly proportional to temperature
Avogadro’s Law
Volume is directly proportional to number of moles
Gay-Lussac’s Law
Pressure is directly proportional to temperature
Effusion Formula
r1/r2 = sqrt(m2/m1)
Pressure equation
force/area
Gas density
m/v or PM/RT
Simple cubic structure
1 atom divided into 8 parts
Body centered cubic structure
1 atom in center and 1 divided into 8 parts
Face centered cubic structure
2 half atoms on each face and 1 divided into 8 parts
Face centered cubic atom amount
4
Body centered cubic atom amount
2
Simple cubic atom amount
1
What is bigger heat of vaporization or heat of fusion
Heat of vaporization
Liquids with high boiling point have … vapor pressure
Lower vapor pressure
Convection
heat transfer within a fluid where hotter, less-dense material rises and cold, dense material sinks
Conduction
heat transfer that occurs between objects by direct contact
Work equation
w=(-P)delta(V)
Postive w
work done on system
Negative w
work done by system
Positive q
energy absorbed
Negative q
energy released
When ΔH°rxn is negative
products are more stable and at lower energy state
When ΔH°rxn is positive
reactants are more stable
Adiabatic
No heat change between surroundings and system
Isothermal
Temperature is constant but heat can come in and out
2nd Law of Thermodynamics
Entropy of universe is always increasing so heat flow from high to low
3rd Law of Thermodynamics
a substance at 0 K has no motion of kinetic energy
Spontanous at all temps
H < 0 and S > 0
Endergonic vs Endothermic
-gonic refers to change in free energy while -thermic refers to change in heat
Galvanic cells convert
chemical to electrical
Electrolytic cells convert
electrical to chemical
Galvanic cells flow
positive to negative
Electrolytic cells flow
negative to positive
Salt bridge found in
galvantic cell
Porous barrier found in
electrolytic cell
Electroplating
plating a thin layer of metal on top of another metal
Which side contains the item to be plated
cathode
Which side contains the metal to be plated
anode
Nuclear fission and fusion both
realease large amounts of energy
What nuclear change does not impact atomic number
Gamma decay