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what is the equation for finding amount left with half lives
N(t) = N_o (1/2) ^(t/(t_1/2))
magic numbers of protons for stability
2, 8, 20, 28, 50, 82
magic numbers of neutrons for stability
2, 8, 20, 28, 50, 82, 126
elements with a high neutron : proton ration undergo what decay process
beta emission
TRUE OR FALSE: all nuclei with 84 or more protons are radioactive
true
nuclei with a low neutron : proton ratio will undergo one of what two processes for decay
positron emission (lighter elements), electron capture
nuclei with an atomic number above 84 will undergo what type of radioactive decay
alpha emission
which type of particle has the highest mass
alpha
what type of particle has the lowest charge
beta
what type of decay has an electron particle on the left side of the equation
electron capture
what particle has no mass no charge and the highest penetrating power
gamma particle
when does a precipitate form?
when Q > Ksp
when Q = Ksp, what can be said about a reaction
it is at equilibrium
how do you calculate cell potential
Ecathode - E anode
in Le Chatliers principle, what changes and what remains the same
[A] or P will change, Kc or Kp will stay the same
reducing the volume of a gaseous mix causes the system to shift in the direction that ____ the number of moles of gas
reduces
true or false: cataylsts increase the rate of the forward reaction only
false
what is an arrhenius acid
when dissolved in H2O, increases H+ ions
what is a bronsted-lowry acid
proton donor
what is a lewis acid
electron pair acceptor
a bronsted-lowry acid must have what quality
one removable proton
a bronsted-lowry base must have at least one what
nonbonding pair of electrons
the transfer of a proton goes from strong acid to _____ base
strong
7 strong acids
HCl, HBr, HI, HNO2, H2SO4, HClO3, HClO4
what is false about polyproctic acids?
the 1st proton is always the hardest to remove
what is molecularity
total number of reactant molecules that collide in an elementary step
a reaction that occurs in a single step is called:
elementary reaction
what step is used to determine rate law
the slowest step
what happens to the intermediates in a reaction
they are made and then used up
what happens to catalysts in a reaction
they are used and then regenerated
what part of a potential energy graph represents the intermediates
a valley between transition states
what represents the Ea in a forward reaction on a potential energy graph
distance from reactants to transition state 1
what is an enzyme
a biological catalyst
true or false: chemical reactions with the same forward and reverse rate are at equilibrium
true
true or false: once equilibrium is achieved, the amount of each reactant and product remains constant
true
pressure is (inversly proportionate / proportionate ) to concentration for gases in a closed system
proportionate
if K > 1, the reaction favors ______
products