Chapter 9 - Covalent Bonding: Orbitals

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16 Terms

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MO1
________ is lower in energy than the 1s orbitals of free hydrogen atoms, while MO2 is higher in energy than the 1s orbitals.
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Diamagnetism
________ causes the substance to be repelled from the inducing magnetic field.
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Paramagnetism
________ causes the substance to be attracted into the inducing magnetic field.
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definite correlations
There are ________ between bond order, bond energy, and bond length.
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d2 sp3 hybridization
A set of five effective pairs around a given atom always requires a trigonal bipyramidal arrangement, which in turn requires ________ of that atom.
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oxygens paramagnetism
The molecular orbital model correctly predicts ________, while the localized electron model predicts a diamagnetic molecule 9.4 Bonding in Heteronuclear Diatomic Molecules.
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molecular orbital
The ________ containing the bonding electron pair shows greater electron probability close to the fluorine.
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resonance
Even with ________ included, the localized electron model does not describe molecules and ions.
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Hybridization
________ is a modification of the localized electron model to account for the observation that atoms often seem to use special atomic orbitals in forming molecules.
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Molecules
________ that require the concept of resonance in the localized electron model can be more accurately described by combining the localized electron and molecular orbital models.
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arrangement of valence electrons
The ________ is represented by the Lewis structure and the molecular geometry can be predicted from the VSEPR model.
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molecular orbitals
To participate in ________, atomic orbitals must overlap in space.
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D2 sp3 hybridization
________ gives six orbitals arranged octahedrally.
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double bond
A(n) ________ acts as one effective electron pair
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Bonding molecular orbital
________: Lower in energy than the atomic orbitals of which it is composed
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Anti bonding molecular orbital
________: Higher in energy than the atomic orbitals of which it is composed

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