Orgo 4th Exam Flashcards 2

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Last updated 4:26 AM on 4/17/26
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14 Terms

1
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alkyl halide to amine

NaCN

  1. LiAlH4, 2. H2O

2
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COOH to amine

  1. SOCl2

  2. excess NH3

  3. excess LiAlH4

  4. H2O

3
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benzene to aniline

HNO3, H2SO4

H2/Pt or Fe H3O+ NaOH

4
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selective amination when aldehyde/ketone present

  1. SnCl2, H3O+

  2. NaOH

5
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azide synthesis

NaN3, LiAlH4, H2O

6
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gabriel synthesis

KOH

RX

H2N-NH2

7
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reductive amination

[H+], NR3 (can change can accordingly)

NaBH3CN

8
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multiple alkylation

CH3I

9
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acylation of amines (can be used as a protecting group)

acid chloride

10
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brominating aniline

para and ortho

11
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monobromination of aniline

acid chloride, pyridine

Br2

H3O+

12
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hofman elimination

  1. excess CH3I

  2. Ag2O, H2O, heat

13
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aryl diazonium salts

NaNO2, HCl less than 5 degrees

14
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how to fluorinate

HBF4