Orgo Mechanisms - Unit 4

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Last updated 2:54 AM on 4/14/26
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5 Terms

1
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Halogenation

anti-addition, Br2 is added, pair of enantiomers in final product

<p>anti-addition, Br2 is added, pair of enantiomers in final product</p>
2
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Halohydrin Formation

anti-addition, one halogen + one -oh group, pair of enantiomers in final product, Cl2 + H2O is added

<p>anti-addition, one halogen + one -oh group, pair of enantiomers in final product, Cl2 + H2O is added</p>
3
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Anti-Dihydroxylation

anti-addition, 1)MCPBA + 2) H2SO4, H2O, pair of enantiomers, adds two -OH groups, “epoxide” intermediate, creation of diols

<p>anti-addition, 1)MCPBA + 2) H2SO4, H2O, pair of enantiomers, adds two -OH groups, “epoxide” intermediate, creation of diols </p>
4
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Syn-Dihydroxylation

syn-addition, 1) OsO4 2) NaHSO3, H2O, two -OH groups added, pair of enantiomers

5
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Oxidative Cleavage/Ozonolysis

1) O3, 2) can be another rxn, sometimes (CH3)2, molecule is cleaved in half and two oxygens are added where the double bond was, ozonide is created as an intermediate

<p>1) O3, 2) can be another rxn, sometimes (CH3)2, molecule is cleaved in half and two oxygens are added where the double bond was, ozonide is created as an intermediate</p>