CHEM 334 Exam 1

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Last updated 2:00 AM on 4/15/26
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34 Terms

1
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<p>(Alkyl Halide) + (Elemental Lithium/THF)</p>

(Alkyl Halide) + (Elemental Lithium/THF)

Organolithium

<p>Organolithium</p>
2
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<p>(Alkyl Halide) + (Elemental Magnesium/THF)</p>

(Alkyl Halide) + (Elemental Magnesium/THF)

Grignard

<p>Grignard</p>
3
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<p>(Organolithium x2) + (Copper Halide)</p>

(Organolithium x2) + (Copper Halide)

Organocuprate

<p>Organocuprate</p>
4
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<p>(Aldehyde) + (1. Organolithium or Grignard 2. H+ wkp)</p>

(Aldehyde) + (1. Organolithium or Grignard 2. H+ wkp)

2° Alcohol

<p>2° Alcohol</p>
5
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<p>(Ketone) + (1. Organolithium or Grignard 2. H+ wkp)</p>

(Ketone) + (1. Organolithium or Grignard 2. H+ wkp)

3° Alcohol

<p>3° Alcohol</p>
6
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<p>(Ester) + (1. Organolithium or Grignard 2. H+ wkp)</p>

(Ester) + (1. Organolithium or Grignard 2. H+ wkp)

3° Alcohol

<p>3° Alcohol</p>
7
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<p>(Acid Chloride) + (1. Organolithium or Grignard 2x | 2. H+ wkp)</p>

(Acid Chloride) + (1. Organolithium or Grignard 2x | 2. H+ wkp)

3° Alcohol

<p>3° Alcohol</p>
8
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<p>(Epoxide) + (1. Organolithium or Grignard 2. H+ wkp)</p>

(Epoxide) + (1. Organolithium or Grignard 2. H+ wkp)

Alcohol

<p>Alcohol</p>
9
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<p>(Aldehyde) (1. NaBH4 2. H+ wkp)</p>

(Aldehyde) (1. NaBH4 2. H+ wkp)

1° Alcohol

<p>1° Alcohol</p>
10
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<p>(Ketone) + (1. NaBH4 2. H+ wkp)</p>

(Ketone) + (1. NaBH4 2. H+ wkp)

2° Alcohol

<p>2° Alcohol</p>
11
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<p>(Ester) + (1. LiAlH4 2. H+ wkp)</p>

(Ester) + (1. LiAlH4 2. H+ wkp)

2x Alcohols

<p>2x Alcohols</p>
12
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<p>(Carboxylic Acid) + (1. LiAlH4 2. H+ wkp)</p>

(Carboxylic Acid) + (1. LiAlH4 2. H+ wkp)

2x Alcohols

<p>2x Alcohols</p>
13
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<p>(1° Alcohol) + (PCC)</p>

(1° Alcohol) + (PCC)

Aldehyde

<p>Aldehyde</p>
14
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<p>(2° Alcohol) + (PCC)</p>

(2° Alcohol) + (PCC)

Ketone

<p>Ketone</p>
15
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<p>(1° Alcohol) + (H2CrO4 or KMnO4)</p>

(1° Alcohol) + (H2CrO4 or KMnO4)

Carboxylic Acid

<p>Carboxylic Acid</p>
16
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<p>(2° Alcohol) + (H2CrO4 or KMnO4)</p>

(2° Alcohol) + (H2CrO4 or KMnO4)

Ketone

<p>Ketone</p>
17
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<p>(Alkene) + (NBS/hv)</p>

(Alkene) + (NBS/hv)

Allylic Bromide

<p>Allylic Bromide</p>
18
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<p>(Benzylic Carbon) + (KMnO4, H+, Δ)</p>

(Benzylic Carbon) + (KMnO4, H+, Δ)

Benzoic Acid

<p>Benzoic Acid</p>
19
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<p>(Alcohol) + (SOCl2/pyridine)</p>

(Alcohol) + (SOCl2/pyridine)

Chloroalkane

<p>Chloroalkane</p>
20
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<p>(Alcohol) + (PBr3)</p>

(Alcohol) + (PBr3)

Bromoalkane

<p>Bromoalkane</p>
21
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<p>(Aldehyde/Ketone) + (Zn(Hg)/HCl)</p>

(Aldehyde/Ketone) + (Zn(Hg)/HCl)

Alkane

<p>Alkane</p>
22
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<p>(Aldehyde/Ketone) + (Hydrazine/KOH)</p>

(Aldehyde/Ketone) + (Hydrazine/KOH)

Alkane

<p>Alkane</p>
23
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<p>(Alcohol) + (TBS-Cl/Imidazole)</p>

(Alcohol) + (TBS-Cl/Imidazole)

Silyl Ether

<p>Silyl Ether</p>
24
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<p>(Silyl Ether) + (1. TBu4F 2. H+ wkp)</p>

(Silyl Ether) + (1. TBu4F 2. H+ wkp)

(Alcohol)

<p>(Alcohol)</p>
25
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<p>(Diene) + (HBr, -78°C)</p>

(Diene) + (HBr, -78°C)

1,2 Kinetic Addition of Bromine

<p>1,2 Kinetic Addition of Bromine</p>
26
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<p>(Diene) + (HBr, 40°C)</p>

(Diene) + (HBr, 40°C)

1,4 Thermodynamic Addition of Bromine

<p>1,4 Thermodynamic Addition of Bromine</p>
27
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<p>(Diene) + (Dienophile) + (Δ)</p>

(Diene) + (Dienophile) + (Δ)

Cyclohexene

<p>Cyclohexene</p>
28
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<p>(Benzene) + (Br2, Δ, FeBr3/AlBr3)</p>

(Benzene) + (Br2, Δ, FeBr3/AlBr3)

Bromobenzene

<p>Bromobenzene</p>
29
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<p>(Benzene) + (Cl2, FeCl3/AlCl3</p>

(Benzene) + (Cl2, FeCl3/AlCl3

Chlorobenzene

<p>Chlorobenzene</p>
30
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<p>(Benzene) + (HNO3, Δ, H2SO4)</p>

(Benzene) + (HNO3, Δ, H2SO4)

Nitrobenzene

<p>Nitrobenzene</p>
31
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<p>(Benzene) + (SO3, H2SO4)</p>

(Benzene) + (SO3, H2SO4)

Benzenesulfonic Acid

<p>Benzenesulfonic Acid</p>
32
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<p>(Benzene) + (Alkyl Chloride, AlCl3)</p>

(Benzene) + (Alkyl Chloride, AlCl3)

Alkylbenzene

<p>Alkylbenzene</p>
33
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<p>(Benzene) + (Acid Chloride, AlCl3)</p>

(Benzene) + (Acid Chloride, AlCl3)

Aryl Ketone

<p>Aryl Ketone</p>
34
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<p>(Benzene) + (Anhydride, AlCl3)</p>

(Benzene) + (Anhydride, AlCl3)

Aryl Ketone

<p>Aryl Ketone</p>