Orgo II Exam I flashcards

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Last updated 5:54 PM on 4/30/26
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74 Terms

1
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  1. NaOH

  2. XR

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LDA, THF

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NaOEt, EtOH

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SOCl2

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PBr3

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TSCl, Pyridine

7
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HX

8
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NaSR

9
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NaOR

10
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NaSH

11
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NaOH

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NaH

13
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RX

14
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  1. NaOH

  2. RX

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  1. NaOH/NaH

  2. R’-X, DMF

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  1. (2) NaOH/NaH

  2. (2) RX

17
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H2SO4 heat

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Excess HX heat

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  1. PBr3

  2. H20

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TMS-Cl, NEt3

21
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TBAF

22
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  1. KOH, RCH2X

  2. H3O+ OR H2N-NH2

23
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  1. NaN3, DMF

  2. LiAlH4

  3. H20

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PCC, CH2Cl2

25
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Na2Cr2O7, H2SO4(aq)

26
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Na2Cr2O7, H2SO4(aq)

28
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Na2Cr2O7, H2SO4(aq) OR PCC, CH2Cl2

29
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  1. LiAlH4

  2. H3O+

OR

NaBH4, CH3OH

30
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NaCN, DMF

31
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  1. Excess LiAlH4

  2. H2O

32
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  1. Excess LiAlH4

  2. H2O

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  1. NaNH2

  2. XCH2R

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H2(g) pd/c

35
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Na(s), NH3(l)

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H2(g), Lindlar’s cat.

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NaOH(aq), Br2

38
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Zn/HCl

39
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NaIO4

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H2O2

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2H2O2

42
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  1. HSCH2CH2SH [H+]

  2. Raney Ni H2(g)

43
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Amine, NaBH3CN, pH=4-6

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NH2R, NaBH3CN, pH=4-6

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  1. NH2NH2

  2. KOH, heat

46
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R–=PPh3

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Ester stabilized ylide

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H2O, H3O+

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  1. Hg(OAc)2, H2O

  2. NaBH4

50
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  1. BH3, THF

  2. H2O2, NaOH

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Br2

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H2(g), pd/c

53
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  1. Br2, H2O

  2. NaOH

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mCPBA

56
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H3O+

57
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  1. OsO4

  2. NMO

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  1. O3

  2. SMe2

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  1. O3

  2. H2O2

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  1. O3

  2. H2O

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  1. O3

  2. H2O

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  1. Nu-

  2. H3O+

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  1. LiAlH4/DIBAH

  2. H2O+

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H2SO4, EtOH

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  1. NaOEt

  2. epoxide

  3. H+

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  1. Excess NaNH2, NH3(l)

  2. H2O

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HCl

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HX

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2 eq. Br2

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H2SO4, H3O+

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  1. R2BH, THF

  2. NaOH, H2O2

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[H+] cat.

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HX

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  1. eq HX