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Thermochemistry
heat changed that occur during chemical or physical reactions
Define energy
the capacity for doing work of supplying heat
chemical potential energy
energy stored within bonds (structural units)
How/why does heat energy transfer from one object to another
because of temperature difference
always goes from hot → cold
aka more energy → less energy
What is the the difference between heat and temperature
temp is the average of kinetic energy
heat is energy
Describe Exothermic and its signs, draw the diagram
heat is lost to the surroundings
container feels hot
the change in heat is negative
energy is lost
Diagram goes straight, peak, downward
Describe Endothermic and its signs, draw the diagram
heat is absorbed from the surroundings
container is cold
the change in heat is positive
energy is gained
diagram starts down, peaks, then goes to the middle
What is a Calorie
the amount of heat required to raise 1 g of water 1 degree Celsius
1 kcal=
1 food calorie
4.18 Joule=
I cal
Is Joule or Calorie bigger
Calorie, like a quater to a dollar
why does water moderate temperature
has a high specific heat
Heat capacity-
amount of heat needed to increase temperature of an object 1 degree celsius
Specific heat-
energy required to change the temp of 1 gram of a substance 1 degree celsius
What is the Energy Equation (labeled)
q= CxMx▵T
q- heat energy gained or lost
c- specific heat (j/g degrees C) or (cal/ g degrees C)
m- mass
▵t- change in temp
NEXT IS ON WARMING COOLING CURVE FOR WATER!!
draw as you go
negative- 0 degrees
A-B:
Solid
The C in q= CxMx▵T for solid is 0.5/g degrees C
0-0 degreese
B-C
heat of fusion
uses Hf x M where Hf=80 cal/g
0-100 degrees
C-D
liquid
The C in q= CxMx▵T for liquid is 1 cal/ g degrees C
100- 100
D-E
heat of vaporization
uses Hv x M where Hv= 540 cal/g
100- 100+
E- F
gas
The C in q= CxMx▵T for gas is 0.4 cal/ g degrees c
What is Hess’s Law
if you add two+ reactions together to get an overall reaction, then you can add the heats of the reactions together to get the heat for the overall reactions:
keep it
flip it
multiply it