Unit 2 List of Alkene Reactions - OCHEM28

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OCHEM28

Last updated 4:09 AM on 10/15/26
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14 Terms

1
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<p>HCl or HBr or HI</p>

HCl or HBr or HI

Hydrohalogenation; H + X ; Markovnikov ; No Stereo

<p><strong>Hydrohalogenation</strong>; H + X ; Markovnikov ; No Stereo</p>
2
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<p>H<sub>2</sub>SO<sub>4</sub>/H<sub>2</sub>O or H<sub>3</sub>O<sup>+</sup></p>

H2SO4/H2O or H3O+

Acid-Catalyzed Hydration; H + OH ; Markovnikov ; No Stereo

<p><strong>Acid-Catalyzed Hydration</strong>; H + OH ; Markovnikov ; No Stereo</p>
3
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<p>1) Hg(OAc)<sub>2</sub> , H<sub>2</sub>O/THF → 2) NaBH<sub>4</sub></p>

1) Hg(OAc)2 , H2O/THF → 2) NaBH4

Oxymercuration-Demercuration; H + OH ; Markovnikov ; Anti

<p><strong>Oxymercuration-Demercuration; </strong>H + OH ; Markovnikov ; Anti</p>
4
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<p>H<sub>2 </sub>/ Pd or Pt or Ni</p>

H2 / Pd or Pt or Ni

Hydrogenation; H + H ; Syn

<p><strong>Hydrogenation; </strong>H + H ; Syn</p>
5
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<p>Br<sub>2</sub> or Cl<sub>2</sub> / CCl<sub>4</sub> or CH<sub>2</sub>Cl<sub>2</sub></p>

Br2 or Cl2 / CCl4 or CH2Cl2

Halogenation; X + X ; Anti

<p><strong>Halogenation</strong>; X + X ; Anti</p>
6
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<p>1) BH<sub>3</sub> • THF → 2) H<sub>2</sub>O<sub>2</sub> , NaOH</p>

1) BH3 • THF → 2) H2O2 , NaOH

Hydroboration-Oxidation; H + OH ; Anti-Markovnikov ; Syn

<p><strong>Hydroboration-Oxidation</strong>; H + OH ; Anti-Markovnikov ; Syn</p>
7
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<p>X<sub>2</sub> / H<sub>2</sub>O</p>

X2 / H2O

Halohydrin Formation; X + OH ; Markovnikov; Anti

<p><strong>Halohydrin Formation; </strong>X + OH ; Markovnikov; Anti</p>
8
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<p>RCO<sub>3</sub>H or McPBA</p>

RCO3H or McPBA

Epoxidation ; O ; Syn

<p><strong>Epoxidation</strong> ; O ; Syn</p>
9
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<p>H<sub>3</sub>O<sup>+</sup></p>

H3O+

Anti-Dihydroxylation (epoxides); OH + OH ; Anti

<p><strong>Anti-Dihydroxylation</strong> (epoxides); OH + OH ; Anti</p>
10
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<p>1) OsO<sub>4</sub> → 2) NaHSO<sub>3</sub></p>

1) OsO4 → 2) NaHSO3

Syn-Dihydroxylation (epoxides); OH + OH ; Syn

<p><strong>Syn-Dihydroxylation </strong>(epoxides)<strong>; </strong>OH + OH ; Syn</p>
11
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term image

Epoxidation (Halohydrin Formation Followed by Base); O ; Anti to Syn

<p><strong>Epoxidation (Halohydrin Formation Followed by Base); O ; Anti to Syn</strong></p>
12
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<p>1) O<sub>3</sub> → 2) Zn, H<sub>3</sub>O<sup>+</sup></p>

1) O3 → 2) Zn, H3O+

Mild Oxidation

<p><strong>Mild Oxidation</strong></p>
13
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<p>KMnO<sub>4</sub></p>

KMnO4

Strong Oxidation ; + CO2

<p><strong>Strong Oxidation ; + CO2</strong></p>
14
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<p>HIO<sub>4</sub></p>

HIO4

Oxidation of Vicinal Diols (Periodic Acid)

<p><strong>Oxidation of Vicinal Diols (Periodic Acid)</strong></p>