Flashcards Chemistry Periodic Trends: Atomic Radius, Ionization Energy & Reactivity

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141 Terms

1
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What is an ion?

An atom or molecule that has gained or lost one or more electrons, resulting in a net electrical charge.

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What is a cation?

A positively charged ion formed when an atom loses one or more electrons.

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What is an anion?

A negatively charged ion formed when an atom gains one or more electrons.

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What is a covalent bond?

A chemical bond formed by the sharing of electron pairs between atoms.

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What is an ionic bond?

A chemical bond formed through the electrostatic attraction between oppositely charged ions.

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What is ionization energy?

The energy required to remove an electron from an atom or ion in its gaseous state.

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What is the ionization trend across a period?

Generally increases due to increasing nuclear charge.

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What is the ionization trend down a group?

Generally decreases due to increased distance from the nucleus and electron shielding.

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What is electronegativity?

A measure of an atom's ability to attract and hold onto electrons in a chemical bond.

10
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Which element is the most electronegative?

Fluorine.

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What is the trend for electronegativity across a period?

Increases across a period.

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What is the trend for electronegativity down a group?

Decreases down a group.

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How does reactivity for metals change down a group?

Increases down a group due to lower ionization energy.

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How does reactivity for nonmetals change up a group?

Increases up a group.

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What is atomic radius?

The distance from the nucleus of an atom to the outermost shell of electrons.

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What is the trend for atomic radius down a group?

Increases down a group.

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What is the trend for atomic radius across a period?

Decreases across a period.

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What is ionic radius?

The radius of an ion in a crystal lattice.

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Are cations larger or smaller than their original atoms?

Smaller, because they lose electrons.

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Are anions larger or smaller than their original atoms?

Larger, because they gain electrons.

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Why are cations smaller?

Losing electrons reduces repulsion and sometimes removes an energy level.

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Why are anions larger?

More electrons create greater repulsion.

23
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What does ionization energy measure?

Energy needed to remove an electron from an atom.

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What is the trend for ionization energy across a period?

Increases across a period.

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What is the trend for ionization energy down a group?

Decreases down a group.

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Which element has the lowest ionization energy?

Francium (Fr).

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Which element has the highest ionization energy?

Helium (He).

28
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Rank Li, C, F by increasing atomic radius.

F < C < Li.

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Rank Li, Na, K by increasing atomic radius.

Li < Na < K.

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Rank Ge, P, O by increasing atomic radius.

O < P < Ge.

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Rank C, N, Al by increasing atomic radius.

N < C < Al.

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Rank Al, Cl, Ga by increasing atomic radius.

Cl < Al < Ga.

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Which is larger: Mg2+ or Mg?

Mg.

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Which is larger: N3- or N?

N3-.

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Which is larger: K+ or Fr+?

Fr+.

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Which is larger: O2- or N3-?

N3-.

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Which is larger: F- or F?

F-.

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What is the largest cation?

Fr+.

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What is the smallest cation?

H+.

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What is the largest anion on this review?

Te2-.

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What is the smallest anion on this review?

F-.

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Rank Mg, Si, S by increasing ionization energy.

Mg < Si < S.

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What is the atomic symbol for Helium?

He

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Rank Mg, Ca, Ba by increasing ionization energy.

Ba < Ca < Mg

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Rank F, Cl, Br by increasing ionization energy.

Br < Cl < F

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Rank Ca, Cu, Kr by increasing ionization energy.

Ca < Cu < Kr

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Rank C, Si, Sn by increasing ionization energy.

Sn < Si < C

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What does electronegativity measure?

An atom's ability to attract shared electrons.

49
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Which direction does electronegativity increase?

Up and to the right.

50
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Which element has the highest electronegativity?

Fluorine (F).

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Which element has the lowest electronegativity?

Francium (Fr).

52
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Do noble gases usually have electronegativity values?

Usually no. Their outer energy levels are full.

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Rank Li, C, N by increasing electronegativity.

Li < C < N

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Rank C, O, Ne by increasing electronegativity.

C < O; Ne has no standard value.

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Rank C, Si, Pb by increasing electronegativity.

Si < Pb < C

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Rank Cs, Ni, F by increasing electronegativity.

Cs < Ni < F

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Rank S, F, He by increasing electronegativity.

S < F; He has no standard value.

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Why are metals less electronegative than nonmetals?

Metals tend to lose electrons instead of attracting them.

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What are metallic properties?

Shiny, malleable, ductile, good conductors, usually lose electrons.

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Which direction do metallic properties increase?

Down and to the left.

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Which element is least metallic?

Helium (He).

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Which element is most metallic?

Francium (Fr).

63
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Rank Li, B, N by increasing metallic properties.

N < B < Li

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Rank Li, Na, K by increasing metallic properties.

Li < Na < K

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Rank Si, P, S by increasing metallic properties.

S < P < Si

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Rank Pb, Po, Rn by increasing metallic properties.

Rn < Po < Pb

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Rank Ra, Sr, Mg by increasing metallic properties.

Mg < Sr < Ra

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What is the shielding effect?

Inner electrons block some nuclear attraction from outer electrons.

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What happens to shielding across a period?

It stays about the same.

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Why is shielding nearly constant across a period?

Electrons are added to the same main energy level.

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Why does shielding increase down a group?

More occupied energy levels are added.

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Which elements have the most shielding?

Elements near the bottom of the periodic table.

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Which elements have the least shielding?

Elements near the top of the periodic table.

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What direction does shielding increase?

Down a group.

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What does it mean for a metal to be reactive?

It easily loses electrons.

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What does it mean for a nonmetal to be reactive?

It easily gains electrons.

77
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Which direction does metal reactivity increase?

Down and to the left.

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Which direction does nonmetal reactivity increase?

Up and to the right, excluding noble gases.

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Rank N, O, F by increasing nonmetal reactivity.

N < O < F

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Rank Li, Na, K by increasing metal reactivity.

Li < Na < K

81
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Rank P, S, Cl by increasing nonmetal reactivity.

P < S < Cl

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Rank Pb, Po, Rn by increasing metal reactivity.

Rn < Po < Pb

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Rank He, I, F by increasing nonmetal reactivity.

He < I < F

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What determines an element's chemical properties?

Number of valence electrons.

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What are valence electrons?

Electrons in the outermost energy level.

86
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How many valence electrons do Group 1 elements have?

1

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How many valence electrons do Group 2 elements have?

2

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How many valence electrons do Group 13 elements have?

3

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How many valence electrons do Group 14 elements have?

4

90
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How many valence electrons do Group 15 elements have?

5

91
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How many valence electrons do Group 16 elements have?

6

92
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How many valence electrons do Group 17 elements have?

7

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How many valence electrons do Group 18 elements have?

8, except He which has 2.

94
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What is the common charge of Group 1 ions?

+1

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What is the common charge of Group 2 ions?

+2

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What is the common charge of Group 13 ions?

+3

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What is the common charge of Group 15 ions?

-3

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What is the common charge of Group 16 ions?

-2

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What is the common charge of Group 17 ions?

-1

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What is the common charge of Group 18 ions?

0