atom + wavelength concepts and quantum mechanics

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Last updated 9:05 PM on 8/13/26
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24 Terms

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the wave function for an electron in an atom does not describe a smeared out electron with a smooth charge density

The electron is either here or there or somewhere else but wherever it is it is a point charge

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Even though a particle itself isn’t a wave what is

It’s properties are

Where it is what it’s doing how much energy it has ( all wave shaped waves of probability not in particular space )

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Measuring a wave

Changes what the wave looks like

Still unknown position

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The measurement of a wave doesn’t

Destroy the wave instead collapse it into a simpler shape

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Some wave measurements can be made together such as

The energy, the magnitude of angular momentum, and its part of orientation

( allowed to be definite same time) but still a little spread this gives emission lines their thickness uncertain energy

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Definiteness gives us info about

Electrons and this info can help us categorize them into shells and orbitals

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Nucleus is made of

Protons, neutrons, and cloud of electrons surrounding it

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The behavior of the protons neutrons and electrons surrounding nucleus is governed by

Wave functions

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Waves are of

Probability (?)

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What do we need if all particles are also waves?

A wave equation to predict their behavior.

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What does the wave equation use?

The total energy of a particle

Hamiltonian (H)

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What is the Hamiltonian (H)?

: It represents the total energy of a particle.

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What is the wave function (Ψ)?

A function that describes the wave properties of a particle.

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What does the equation involving H and Ψ contain?

It contains all the wave properties of a particle.

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What problem does the wave model solve with the old orbit model?

: Instead of electrons continuously emitting light and collapsing into the nucleus, the electron is described as a wave.

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What surrounds the nucleus in the wave model?

A cloud of electrons

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What might the electron cloud represent?

A wave of probability

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Electron = not a little particle following a fixed orbit → described by a wave/probability cloud around the nucleus

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: What is quantum mechanics?

The study of how very small particles, like electrons, behave, including their wave-like behavior

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Why is quantum mechanics needed to describe electrons?

Because electrons behave like waves as well as particles, so the old orbit model doesn’t accurately describe them.

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What does quantum mechanics use to describe an electron?

A wave function

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What does the wave function describe?

The wave properties/probability of a particle.

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How is an electron represented in the quantum mechanical model?

As a cloud of probability surrounding the nucleus, rather than a particle following a fixed orbit

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