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120 Terms

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grain growth

The increase in average grain size of a polycrystalline material; for most materials, an elevated-temperature heat treatment is necessary.

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ductile fracture

A mode of fracture attended by extensive gross plastic deformation.

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brittle fracture

Fracture that occurs by rapid crack propagation and without appreciable macroscopic deformation.

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transgranular fracture

Fracture of polycrystalline materials by crack propagation through the grains.

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intergranular fracture

Fracture of polycrystalline materials by crack propagation along grain boundaries.

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fracture mechanics

A technique of fracture analysis used to determine the stress level at which preexisting cracks of known size will propagate, leading to fracture.

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fracture toughness

The measure of a material's resistance to fracture when a crack is present.

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Charpy test

One of two tests (see also Izod test) that may be used to measure the impact energy or notch toughness of a standard notched specimen.

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Izod test

One of two tests (see also Charpy test) that may be used to measure the impact energy of a standard notched specimen.

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impact energy (notch toughness)

A measure of the energy absorbed during the fracture of a specimen of standard dimensions and geometry when subjected to very rapid (impact) loading.

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ductile-to-brittle transition

The transition from ductile to brittle behavior with a decrease in temperature exhibited by some low-strength steel (BCC) alloys.

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fatigue

Failure, at relatively low stress levels, of structures that are subjected to fluctuating and cyclic stresses.

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fatigue limit

The maximum stress amplitude level below which a material can endure an essentially infinite number of stress cycles without failing.

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fatigue strength

The maximum stress level that a material can sustain without failing for a specified number of cycles.

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fatigue life

The total number of stress cycles that cause a fatigue failure at some specified stress amplitude.

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case hardening

Hardening of the outer surface of a steel component by a carburizing or nitriding process.

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thermal fatigue

A type of fatigue failure in which the cyclic stresses are introduced by fluctuating thermal stresses.

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corrosion fatigue

A type of failure that results from the simultaneous action of a cyclic stress and chemical attack.

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creep

The time-dependent permanent deformation that occurs under stress; important at elevated temperatures.

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component

A chemical constituent (element or compound) of an alloy used to specify its composition.

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system

A specific body of material or a series of possible alloys consisting of the same components.

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solubility limit

The maximum concentration of solute that may be added without forming a new phase.

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phase

A homogeneous portion of a system that has uniform physical and chemical characteristics.

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equilibrium (phase)

The state of a system in which the phase characteristics remain constant over indefinite time periods.

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free energy

A thermodynamic quantity that is a function of both internal energy and entropy of a system.

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phase equilibrium

The state of a system at equilibrium regarding its phases.

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metastable

A nonequilibrium state that may persist for a very long time.

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phase diagram

A graphical representation of the relationships among environmental constraints, composition, and regions of phase stability.

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isomorphous

Having the same structure; in the phase diagram sense, having the same crystal structure or complete solid solubility.

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tie line

A horizontal line across a two-phase region of a binary phase diagram indicating equilibrium compositions.

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lever rule

A mathematical expression to compute phase amounts in a two-phase alloy at equilibrium.

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solvus line

The locus of points on a phase diagram representing the limit of solid solubility as a function of temperature.

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solidus line

On a phase diagram, the locus of points at which solidification or melting begins during equilibrium cooling.

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liquidus line

On a binary phase diagram, the line separating liquid and liquid + solid-phase regions.

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eutectic reaction

A reaction where a liquid phase transforms isothermally and reversibly into two solid phases upon cooling.

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eutectic structure

A two-phase microstructure resulting from the solidification of a liquid having the eutectic composition.

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eutectic phase

One of the two phases found in the eutectic structure.

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primary phase

A phase that exists in addition to the eutectic structure.

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microconstituent

An element of the microstructure with identifiable structure, potentially consisting of more than one phase.

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terminal solid solution

A solid solution that exists over a composition range extending to either composition extreme of a binary phase diagram.

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intermetallic compound

A compound of two metals that has a distinct chemical formula, appearing as an intermediate phase on a phase diagram.

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eutectoid reaction

A reaction where one solid phase transforms isothermally and reversibly into two new solid phases upon cooling.

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peritectic reaction

A reaction in which a solid and a liquid phase transform into a different solid phase upon cooling.

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congruent transformation

A transformation of one phase to another of the same composition.

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Gibbs phase rule

An equation that expresses the relationship between the number of phases present and the number of externally controllable variables.

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ferrite (ceramic)

Ceramic oxide materials composed of both divalent and trivalent cations.

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austenite

Face-centered cubic iron; also iron and steel alloys that possess the FCC crystal structure.

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cementite

Iron carbide (Fe3C).

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pearlite

A two-phase microstructure found in steels and cast irons, consisting of alternating layers of ferrite and cementite.

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hypoeutectoid alloy

An alloy for which the concentration of solute is less than the eutectoid composition.

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proeutectoid ferrite

Primary ferrite that exists alongside pearlite for hypoeutectoid steels.

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proeutectoid cementite

Primary cementite that exists alongside pearlite for hypereutectoid steels.

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transformation rate

The reciprocal of the time necessary for a reaction to proceed halfway to completion.

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phase transformation

A change in the number and/or character of the phases that constitute the microstructure of an alloy.

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nucleation

The initial stage in a phase transformation indicated by the formation of small particles of the new phase.

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growth (particle)

The increase in size of a particle of a new phase during a phase transformation.

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kinetics

The study of reaction rates and the factors that affect them.

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thermally activated transformation

A reaction that depends on atomic thermal fluctuations to occur.

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supercooling

Cooling to below a phase transition temperature without the occurrence of the transformation.

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superheating

Heating to above a phase transition temperature without the occurrence of the transformation.

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isothermal transformation (TTT diagram)

A plot of temperature vs. the logarithm of time for a steel alloy used to determine when transformations begin and end.

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coarse pearlite

Pearlite with relatively thick alternating ferrite and cementite layers.

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fine pearlite

Pearlite with relatively thin alternating ferrite and cementite layers.

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bainite

An austenitic transformation product found in steels and cast irons that forms between pearlite and martensite temperatures.

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spheroidite

Microstructure consisting of spherelike cementite particles within a ferrite matrix.

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martensite

A metastable iron phase supersaturated in carbon, resulting from a diffusionless transformation from austenite.

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athermal transformation

A nonthermally activated reaction, typically diffusionless and occurring quickly.

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plain carbon steel

A ferrous alloy where carbon is the primary alloying element.

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alloy steel

A ferrous alloy containing appreciable concentrations of alloying elements to improve properties.

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continuous-cooling transformation (CCT) diagram

A plot indicating when transformations occur during continuous cooling of a steel alloy.

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tempered martensite

The product of tempering heat treatment of martensitic steel, consisting of small, uniformly dispersed cementite particles.

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ferrous alloy

A metal alloy for which iron is the prime constituent.

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high-strength, low-alloy (HSLA) steel

Strong, low-carbon steels with less than about 10 wt% total of alloying elements.

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stainless steel

A steel alloy highly resistant to corrosion, predominantly alloyed with chromium.

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cast iron

A ferrous alloy with carbon content greater than the maximum solubility in austenite at the eutectic temperature.

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gray cast iron

A cast iron alloyed with silicon where graphite exists in the form of flakes.

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ductile iron

A cast iron alloyed with silicon and magnesium/cerium, with free graphite in nodular form.

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white cast iron

A low-silicon, very brittle cast iron where carbon is in a combined form as cementite.

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malleable cast iron

White cast iron heat-treated to convert cementite into graphite clusters, resulting in a relatively ductile form.

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compacted graphite iron

A cast iron with silicon and magnesium, where graphite exists as wormlike particles.

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wrought alloy

A metal alloy that is ductile and can be worked during fabrication.

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brass

A copper-rich copper-zinc alloy.

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bronze

A copper-rich copper-tin alloy; can also include aluminum, silicon, and nickel bronzes.

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temper designation

A letter-digit code designating the treatment of a metal alloy.

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specific strength

The ratio of tensile strength to specific gravity for a material.

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nonferrous alloys

Alloys in which iron is not the prime constituent.

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hot working

Metal-forming operations performed above a metal's recrystallization temperature.

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cold working

Plastic deformation of a metal at a temperature below that at which it recrystallizes.

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forging

Mechanical forming of metal by heating and hammering.

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rolling

Metal-forming operation that reduces thickness of sheet stock by using grooved rolls.

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extrusion

A forming technique in which material is forced through a die orifice.

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drawing (metals)

Technique to fabricate metal wire and tubing by pulling material through a die.

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powder metallurgy (P/M)

Fabrication of metal pieces from compacted metal powders followed by heat treatment.

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welding

A technique for joining metals by melting the pieces to be joined, possibly using filler metal.

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annealing

A heat treatment process altering the microstructure and properties of a material.

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process annealing

Annealing of previously cold-worked products below the lower critical temperature.

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stress relief

A heat treatment to remove residual stresses in materials.

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lower critical temperature

Temperature below which, under equilibrium conditions, all austenite transforms into ferrite and cementite.

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upper critical temperature

Minimum temperature above which, under equilibrium conditions, only austenite is present.

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normalizing

For ferrous alloys, austenitizing above the upper critical temperature, then cooling in air.