Organic Pathways

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Description and Tags

Chemistry

9 Terms

1
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Halogenoalkane —> Alcohol

Nucleophilic substitution

Aqueous NaOH/KOH

Heat under reflux

2
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Halogenoalkane —> Nitrile

Nucleophilic substitution

KCN in ethanol

Heat under reflux

3
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Halogenoalkane —> 1º amine

Nucleophilic substitution

Excess NH3 in ethanol

Heat under pressure

4
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Halogenoalkane —> Alkene

Elimination

KOH in ethanol

Heat under reflux

5
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Alkene —> Dihalogenoalkane

Electrophilic addition

Br2

Room temperature

6
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Alkene —> Halogenoalkane

Electrophilic addition

HBr

Room temperature

7
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Alkene —> Alkyl hydrogensulfate —> Alcohol

Electrophilic addition

Conc. H2SO4

Room temperature


Hydrolysis

Water

Warm mixture

8
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1º Alcohol —> Aldehyde

Oxidation

Acidified K2Cr2O7

Heat and distil

9
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2º Alcohol —> Ketone

Oxidation

Acidified K2Cr2O7

Heat