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Chemistry

Chemical Reactions

Purdue University

CHM 25600

Last updated 8:20 PM on 10/17/26

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48 Terms

1

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<p>acyl chloride + H2O → ?</p>

acyl chloride + H2O → ?

carboxylic acid (hydrolysis)

<p>carboxylic acid (hydrolysis)</p>

2

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<p>Acid chloride + ROH → ?</p>

Acid chloride + ROH → ?

Ester + HCl

<p>Ester + HCl</p>

3

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Acid chloride + NH₃ or amine → ?

Amide + HCl.

4

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<p>Acyl chloride + R₂CuLi (Gilman reagent)→ ?</p>

Acyl chloride + R₂CuLi (Gilman reagent)→ ?

Ketone

<p>Ketone </p>

5

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<p>Acyl chloride + RMgBr (Grignard reagent)→ ?</p>

Acyl chloride + RMgBr (Grignard reagent)→ ?

Tertiary alcohol after hydrolysis.

<p>Tertiary alcohol after hydrolysis.</p>

6

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Reagent that converts carboxylic acid to acid chloride?

SOCl₂ + Base

7

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Anhydride + water → ?

2 carboxylic acids.

8

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Anhydride + ROH → ?

Ester + carboxylic acid.

9

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Anhydride + amine → ?

Amide + carboxylic acid.

10

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Ester + H₂O / acid or base → ?

Carboxylic acid + alcohol (hydrolysis).

11

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Ester + NH₃ → ?

Amide + alcohol.

12

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Ester + LiAlH₄ → ?

Primary alcohol (reduction).

13

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Ester + RMgBr → ?

Tertiary alcohol (2 additions).

14

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Amide + LiAlH₄ → ?

Amine (reduction).

15

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Amide + water + heat (acid/base) → ?

Carboxylic acid (hydrolysis).

16

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<p>Nitrile + LiAlH₄ → ?</p>

Nitrile + LiAlH₄ → ?

Primary amine.

<p>Primary amine.</p>

17

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<p>Nitrile + H₂O + heat → ?</p>

Nitrile + H₂O + heat → ?

Carboxylic acid.

<p>Carboxylic acid.</p>

18

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<p>ketone + (1)NaBH₄, (2)H<sup>+</sup> → ?</p>

ketone + (1)NaBH₄, (2)H⁺ → ?

secondary alcohol

<p>secondary alcohol</p>

19

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(Aldehydes, ketones, esters, acids, amides, epoxides and nitriles) + (1)LiAlH₄ , (2)H⁺→ ?

alcohols or amines.

20

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<p>What does PCC oxidize a primary alcohol to?</p>

What does PCC oxidize a primary alcohol to?

Aldehyde.

<p>Aldehyde.</p>

21

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<p>What does Jones reagent oxidize a primary alcohol to?</p>

What does Jones reagent oxidize a primary alcohol to?

Carboxylic acid.

<p>Carboxylic acid.</p>

22

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<p>Aldehyde or ketone + Grignard reagent → ?</p>

Aldehyde or ketone + Grignard reagent → ?

Alcohol (1°, 2°, or 3° depending on structure).

<p>Alcohol (1°, 2°, or 3° depending on structure).</p>

23

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<p>Aldol condensation product after dehydration?</p>

Aldol condensation product after dehydration?

α,β-hydroxy dicarbonyl

<p>α,β-hydroxy dicarbonyl</p>

24

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<p>What does Claisen condensation form?</p>

What does Claisen condensation form?

β-keto ester or β-diketone.

<p>β-keto ester or β-diketone.</p>

25

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<p>Aldehyde or ketone + 2ROH + acid → ?</p>

Aldehyde or ketone + 2ROH + acid → ?

Acetal (protecting group).

<p>Acetal (protecting group).</p>

26

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<p>Acetal + H2O + ROH → ?</p>

Acetal + H2O + ROH → ?

aldehyde or ketone

27

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<p>What does Jones reagent oxidize a secondary alcohol to?</p>

What does Jones reagent oxidize a secondary alcohol to?

Ketone

28

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<p>Aldehyde + (1)NaBH₄, (2)H<sup>+</sup> → ?</p>

Aldehyde + (1)NaBH₄, (2)H⁺ → ?

primary alcohol

<p>primary alcohol</p>

29

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<p>Diels Alders + cis alkene</p>

Diels Alders + cis alkene

meso compound

<p>meso compound</p>

30

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<p>Diels alder + trans alkene</p>

Diels alder + trans alkene

enantiomers

<p>enantiomers</p>

31

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<p>Nitration rxn</p>

Nitration rxn

note* this rxn has sigma complexes

<p>note* this rxn has sigma complexes</p>

32

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<p>Sulfonylation rxn</p>

Sulfonylation rxn

note* this rxn has sigma complexes

<p>note* this rxn has sigma complexes</p>

33

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<p>Carbonyl + primary amine </p>

Carbonyl + primary amine

imine

<p>imine</p>

34

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<p>carbonyl + secondary amine</p>

carbonyl + secondary amine

enamine

<p>enamine</p>

35

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<p>amide + H3O<sup>+</sup> + heat</p>

amide + H3O⁺ + heat

Carbo. acid + amine

<p>Carbo. acid + amine</p>

36

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<p>Ester hydrolysis: base catalyzed</p>

Ester hydrolysis: base catalyzed

carbo. acid + acid

<p>carbo. acid + acid</p>

37

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<p>Ester hydrolysis: acid catalyzed </p>

Ester hydrolysis: acid catalyzed

carbo. acid + acid

<p>carbo. acid + acid</p>

38

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<p>Electrophilic Aromatic Substitution rxn</p>

Electrophilic Aromatic Substitution rxn

note* this rxn has sigma complexes

<p>note* this rxn has sigma complexes</p>

39

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<p>Bromination(chlorination) EAS rxn</p>

Bromination(chlorination) EAS rxn

note* this rxn has sigma complexes

<p>note* this rxn has sigma complexes</p>

40

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<p>Activating (EDG) disubstitution</p>

Activating (EDG) disubstitution

2 products: ortho and para

<p>2 products: ortho and para</p>

41

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<p>Deactivating (EWG) disubstitution</p>

Deactivating (EWG) disubstitution

1 product: meta

<p>1 product: meta</p>

42

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<p>Decarboxylation rxn</p>

Decarboxylation rxn

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43

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<p>Esterification rxn</p>

Esterification rxn

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44

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<p>Carbanion addition</p>

Carbanion addition

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45

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<p>Sn2 - alkylations</p>

Sn2 - alkylations

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46

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<p>cbz protection</p>

cbz protection

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47

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<p>Boc protection</p>

Boc protection

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48

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<p>carboxylic acid + ROH + H<sup>+ </sup>(Fischer esterification)</p>

carboxylic acid + ROH + H⁺(Fischer esterification)

Ester + H2O

<p>Ester + H2O</p>