Reactions (EAS) and adjacent ones

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Last updated 3:35 AM on 10/16/26
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26 Terms

1
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Br2/FeBr3 or Cl2/FeCl3

halogenation of benzene

<p>halogenation of benzene</p>
2
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HNO3/H2SO4

nitration of benzene (NO2)

<p>nitration of benzene (NO2)</p>
3
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SO3/H2SO4

Sulfonation of Benzene

<p>Sulfonation of Benzene</p>
4
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RCl/AlCl3

Friedel-Crafts Alkylation

<p>Friedel-Crafts Alkylation</p>
5
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ClCOR/AlCl3

Friedel-Crafts Acylation

<p>Friedel-Crafts Acylation</p>
6
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product of nitration of benzene

NO2

7
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Product of sulfonation of benzene

SO3H

8
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Limitations of Alkylation

1. Cannot alkylate rings with EWG

2. Rxn is hard to control, so will receive multiple alkylations on same molecule

3. Carbocation Rearrangement: may not get desired product

9
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Limitations of acetylation

Can't react with EWG

10
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CO, HCl/AlCl3, CuCl

add aldehyde to a ring

<p>add aldehyde to a ring</p>
11
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Zn(Hg), HCl

reduces carbonyl to alkane

<p>reduces carbonyl to alkane</p>
12
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1. Zn/HCl 2.NaOH

Reduces Nitro group to Amino

<p>Reduces Nitro group to Amino</p>
13
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<p>Is Ester an EWG or EDG?</p>

Is Ester an EWG or EDG?

EDG

14
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<p>Is alkoxide an EWG or EDG?</p>

Is alkoxide an EWG or EDG?

Strongly EDG

15
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<p>Is hydroxy an EWG or EDG?</p>

Is hydroxy an EWG or EDG?

EDG

16
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<p>is Amide an EWG or EDG?</p>

is Amide an EWG or EDG?

EDG

17
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<p>is Amine an EWG or EDG?</p>

is Amine an EWG or EDG?

Strongly EDG

18
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<p>is Methyl an EWG or EDG?</p>

is Methyl an EWG or EDG?

Weakly EDG

19
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<p>Is ethyl an EWG or EDG?</p>

Is ethyl an EWG or EDG?

Weakly EDG

20
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<p>Is isopropyl an EWG or EDG</p>

Is isopropyl an EWG or EDG

Weakly EDG

21
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<p>Is Carbonyl an EWG or EDG?</p>

Is Carbonyl an EWG or EDG?

EWG

22
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<p>Is Sulfonyl an EWG or EDG?</p>

Is Sulfonyl an EWG or EDG?

EWG

23
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<p>Is cyano an EWG or EDG?</p>

Is cyano an EWG or EDG?

Strongly EWG

24
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<p>Is Nitro an EWG or EDG?</p>

Is Nitro an EWG or EDG?

Strongly EWG

25
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<p>Is haloalkyl an EWG or EDG?</p>

Is haloalkyl an EWG or EDG?

Strongly EWG

26
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<p>Is Ammonium an EWG or EDG?</p>

Is Ammonium an EWG or EDG?

Strongly EWG