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What is a chemical reaction?
The process by which one or more substances are changed into one or more different substances
What is the Law of Conservation of Mass?
The total mass of the reactants must equal the total mass of products for any given chemical reaction
What does a chemical equation represent?
With symbols and formulas it represents the identities and relative amounts of the reactants and products in a chemical reaction
What are indications of a chemical reaction?
Heat and light emitted
Production of a gas
Formation of a precipitate
Color change
What are characteristics of chemical equations?
Equation must represent all known facts
Must contain the correct formulas for the reactants & products
The law of conservation of mass must be satisfied
What are diatomic molecules?
They do not exist as a single molecule
What are the diatomic moelcules?
H₂, N₂, O₂, F₂, Cl₂, Br₂, I₂
What is a way to memorize the diatomic molecules?
HOFBrINCl
What are coefficients used for in a chemical equation?
To equalize the # of atoms, coefficients are added where necessary
Small whole # in front of a chemical formula.
If no coefficient, assume to be 1
What is a word equation?
A word equation is an equation where reactants and products are represented by words
Does not give amount of reactants/products
What is an example of a word equation?
Methane + oxygen → carbon dioxide + water
What does a formula equation represent?
A formula equation represents the reactants and products of a chemical equation by their symbols or formulas
What does a balanced formula equation provide?
Both qualitative and quantitative data
CH4(g) + 2O2(g) → CO2(g) + 2H2O(g)
What are the states of reactants and products?
(s) - solid
(l) - liquid
(g) - gas
(aq) - aqueous: "Dissolved" in water
What do coefficients indicate?
Coefficients indicate relative amounts of reactants and products
What does a chemical reaction give?
The smallest whole number ratio
What can relative mass of products/reactants be determined from?
Reaction's coefficients
What does the reverse reaction have the same amount as?
The reverse reaction has the same relative amounts of substances as the forward reaction
What are the rules to balancing chemical equations?
List atoms on both sides of the reaction
Balance different atoms one at a time
1st balance elements that appear only once on each side of the equation
Balance polyatomic ions that appear on both sides of the equation
Balance H and O LAST
Count to make sure atoms of the same elements are equal
What is methane?
CH₄
What must you assume while balancing chemical equations?
Everything is unbalanced
What are the types of chemical reactions?
Synthesis, decomposition, single replacement, double displacement, and combustion
What is a synthesis reaction?
A synthesis/composition reaction is when two or more substances combine to form one new product
A + X -> AX
What are oxides?
Reactions of elements with oxygen produce an oxide of the element
Both metals and non-metals!
2Mg(s) + O₂(g) -> 2MgO(s)
S₈ (s) + 8O₂(g) ->
What do most metals react with?
Most metals react with group 17 elements (halogens) to form ionic compounds (halides)
Group one forms MX - NaCL -> 1:1 ratio
Group two forms MX₂ -MgF₂ -> 1:2 ratio
What element is particularly reactive with metals?
Fluorine
How is metal hydroxides formed?
Oxides of active metals (highly reactive metals) react with water to form metal hydroxides
CaO (s) + H₂O (l) -> Ca(OH)₂
How are oxyacids formed?
Many oxides of non-metals react with water to produce oxyacids
Acid rain = non metal oxide + H₂O
Nonmetal oxide = SO₂ or NO₂
What is a decomposition reaction?
A single compound undergoes a reaction that produces 2 or more simpler substances (opposite of a synthesis reaction)
AX -> A + X
When can a decomposition reaction take place?
A decomposition reaction can only take place when energy, in the form of electricity or heat, is added
What does decomposition of binary compounds turn into?
Decomposition of Binary compounds breaks compound into its elements
Do oxides of less active metals decompose?
Yes, oxides of less-active metals also decompose into their elements when heated
What do metal carbonates break down to produce?
Metal carbonates break down to produce a metal oxide and CO2 gas
CaCO₃, MgCO₃
What do metal hydroxides yield?
Metal hydroxides (except group 1) yield metal oxides and water
What do metal chlorates produce?
Metals chlorates produces a metal chloride and oxygen
Fe(ClO₃)₃ + CaClO₂
What is a single replacement reaction?
One element replaces a similar element in a compound
A + BX -> AX + B
Y + BX -> BY + X
Where do single replacement reactions usually occur?
In aqueous solutions
What does metal replace in single replacement reactions?
Metal replaces metal in a compound
What occurs during a replacement of hydrogen in water by a metal in a single replacement reaction?
Group 1 elements react vigorously with water to produce metal hydroxides and hydrogen gas
Less-active metals react to produce metal oxides and hydrogen gas
What occurs during the replacement of hydrogen in an acid by a
metal?
More active metals can replace the hydrogen in acids like, HCl, and H2SO4 to produce a metal compound (salt) and
hydrogen gas
What occurs during the replacement of halogens?
One halogen can replace another less-active halogen
Each halogen is less active than the one above it
What are double replacement actions?
The ions of two compounds exchange places in an aqueous solution to form two new compounds
AB + CD → AD + CB
What are double replacement reactions like?
One compound is usually a precipitate, an insoluble gas, or a molecular compound like water
The other compound formed is soluble and remains in solution
What is a precipitate?
A precipitate is an insoluble (or slightly soluble) compound
How does a precipitate form?
Precipitate forms because of the strong attractive forces between ions
How does a gas form?
Insoluble gas forms and bubbles out of the solution
How does water form?
Very stable molecular compound (water) forms
What are combustion reactions?
A substance combine with oxygen releasing a large amount of energy in the form of light and heat
What is an example of a combustion reaction?
The burning of natural gas, propane, gasoline, and wood are combustion reactions
What are the most reactive metals?
Potassium, Sodium, Calcium, Magnesium, Aluminum, Zinc, Iron, Tin and Lead are more reactive than hydrogen
What are the least reactive metals?
Copper, Mercury, Silver, and God are less reactive than hydrogen
What elements react with H+ (aq) and H₂O (l) to make H₂ (g)?
Lithium, Potassium, Barium, and Calcium
What elements react with H+ (aq) and H₂O (g) to make H₂ (g)?
Magnesium, Aluminum, Manganese, Zinc, Chromium, and Iron
What elements react with H+ (aq) to make H₂ (g)?
Cobalt, Nickel, and Tin
What elements do not react with H+ (aq)?
Copper, Silver, Mercury, Platinum, and Gold
Think jewelry
When using subscript with hydroxide what do you need to add?
Parentheses - (OH)₂
What are examples of synthesis reactions?
Elements + oxygen -> "oxide" compound (can be metal/nonmetal oxides)
Elements + elements -> compound
Compound + compound -> compound
Metal oxide H₂O -> metal hydroxide
What is the formula for single replacement reactions?
A + BX -> AX + B (cation swapped out for cation)
Y + BX -> BY + X (anion swapped out for anion)
Cation is written first (positive ion)
How can you tell from the periodic table which elements are most active when bonding with another element?
Diagonal trend - Li most active while Au/Pt least active
In single replacement reactions what does metal replace in water?
Metal replaces H in water