Exam 3 - Alkene Reactions & Reagents

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15 Terms

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<p>H₂</p><p>Pd, Pt, Ni</p>

H₂

Pd, Pt, Ni

Catalytic Hydrogenation/Reduction

Syn addition

<p>Catalytic Hydrogenation/Reduction</p><p>Syn addition</p>
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<p>HX (for the example, use HBr)</p>

HX (for the example, use HBr)

Hydrohalogenation

Markovnikov

<p>Hydrohalogenation</p><p>Markovnikov</p>
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<p>HBr, Peroxide (R−O−O−R)</p>

HBr, Peroxide (R−O−O−R)

Hydrobromination with Peroxide

Anti-Markov

*

<p>Hydrobromination with Peroxide</p><p>Anti-Markov</p><p>*</p>
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<p>H₂SO₄</p>

H₂SO₄

Addition of Sulfuric Acid

markovnikov

*

<p>Addition of Sulfuric Acid</p><p>markovnikov</p><p>*</p>
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<ol><li><p>H₂SO₄</p></li><li><p>H₂O </p></li></ol><p></p>

  1. H₂SO₄

  2. H₂O


Acid-Catalyzed Hydration

Markovnikov

*

<p>Acid-Catalyzed Hydration</p><p>Markovnikov</p><p>*</p>
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<p>1.) BH₃, THF</p><p>2.) H₂O₂, OH-</p>

1.) BH₃, THF

2.) H₂O₂, OH-

Hydroboration Oxidation

Anti-markovnikov

Syn addition

<p>Hydroboration Oxidation</p><p>Anti-markovnikov</p><p>Syn addition</p>
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<p>1.) Hg(OAc)₂, H₂O</p><p>2.) NaBH₄, OH-</p>

1.) Hg(OAc)₂, H₂O

2.) NaBH₄, OH-

Oxymercuration-Demercuration

Markovnikov

<p>Oxymercuration-Demercuration</p><p>Markovnikov</p>
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<p>X₂</p>

X₂

Halogenation

Anti-addition

<p>Halogenation</p><p>Anti-addition</p>
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<p>Br₂, H₂O</p>

Br₂, H₂O

Halohydrin Formation

Markovnikov

Anti addition

<p>Halohydrin Formation</p><p>Markovnikov</p><p>Anti addition</p>
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<p>CH₂</p><p>CH₂I₂, Zn(Cu)</p><p>OH-, HCCl₃</p>

CH₂

CH₂I₂, Zn(Cu)

OH-, HCCl₃

Addition of Carbene/Simmons-Smith

Syn addition

<p>Addition of Carbene/Simmons-Smith</p><p>Syn addition</p>
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<p>1.) OsO₄, Pyridine</p><p>2.) NaHSO₄, H₂O</p>

1.) OsO₄, Pyridine

2.) NaHSO₄, H₂O

Syn-Dihydroxylation

<p>Syn-Dihydroxylation</p>
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<p>1.) KMnO₄, HO-</p><p>2.) H₂O, cold</p>

1.) KMnO₄, HO-

2.) H₂O, cold

Syn-Dihydroxylation

<p>Syn-Dihydroxylation</p>
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what reactions are anti markovnikov?

Hydrobromination with peroxide

Hydroboration Oxidation

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what reactions are anti-addition?

Halogenation

Halohydrin formation

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what reactions are syn addition?

Catalytic hydrogenation

Hydroboration oxidation

Addition of Carbene

Dihydroxylation