orgo ch. 8 reactions

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11 Terms

1
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Catalytic hydrogenation

syn addition, no rearrangement

<p>syn addition, no rearrangement </p>
2
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hydrohalogenation

markovnikov, can rearrange, common solvents: DCM(CH2Cl2), CCl4, non polar aprotic, {can use ROOR to make it anti mark)

<p>markovnikov, can rearrange, common solvents: DCM(CH2Cl2), CCl4, non polar aprotic, {can use ROOR to make it anti mark)</p>
3
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Halogenation

anti-addition, more substituted—> faster

<p>anti-addition, more substituted—&gt; faster</p>
4
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Halohydrin Formation

anti addition, Markovnikov

<p>anti addition, Markovnikov</p>
5
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Acid catalyzed hydration

Mark, can rearrange (adds OH and H)

<p>Mark, can rearrange (adds OH and H)</p>
6
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oxymercuration-demercuration

anti-addition, mark, 2 stages, no rearrangement (adds OH and H)

<p>anti-addition, mark, 2 stages, no rearrangement (adds OH and H)</p>
7
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Hydroboration oxidation

anti mark, syn, THF

<p>anti mark, syn, THF</p>
8
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Syn dihydration

1 product, syn

<p>1 product, syn </p>
9
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anti dihydration

forms epoxide first with mcPBA, anti

10
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epoxidation

O added, syn, forms carboxylic acid

<p>O added, syn, forms carboxylic acid </p>
11
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ozonolysis

cleaves

<p>cleaves </p>