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what are metamorphic rocks
Rocks that change structure or composition without melting due to pressure or temperature changes
Pressure/temperature change can cause the form of the rock to change in two ways
Form = texture/structure and composition
Protolith = original rock
Note: if rock melts it then becomes an igneous rock NOT metamorphic
What causes a rock to undergo metamorphism
Subduction of plates | Increase in pressure and temperature in a subduction zone
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Collision zones | Collision between continental and continental lithosphere
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Meteorites | Impact shock of meteorites landing
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how does metamorphism change rock texture
Pressure/temperature change can cause the texture of the rock to change
Chemical composition remains the same
Texture = grain shale and orientation
Layers inside rock allow us to tell direction of forces
Direction or force is perpendicular to plane of rock layer
example of metamorphosed rock changing texture
E.g. Marble
Comes from fossiliferous limestone
Both made out of calcite and some dolomite
Main differences
Limestone contains fossils
Fossils cannot be preserved when exposed to high pressure and temperature
Marble has layering
Marble flows
Due to high temperature
Limestone has fractures
Grains in marble are more uniform
Grains in limestone are more varied in size and shape
example of how metamorphism changes rock chemical compositoin
shale -> schist
Shale
Very fine grains
Clay minerals
Small fragments of rock
Schist
Contains elongated course minerals (chloritoid)
Chloritoid not originally in shale
Metamorphism increased grain size and made new minerals
Economic significance of metamorphic rocks
Create rare earth minerals
Create ore deposits (e.g. vein gold deposits)
Metamorphism during subduction = deep crustal rocks release fluid = fluid moves through overlying rocks
Hotter temperature in lower crust carries gold to upper crustal levels
Gold occurs in quartz, carbonate veins, adjacent rocks or faults
How to identify a metamorphic rock
Metamorphic texture
Grains have grown in place and interlock
Metamorphic minerals
Presence of new minerals that can only form under metamorphic conditions
These minerals are not stable where igneous or sedimentary rocks form
Metamorphic foliation
repetition of planar surfaces within a rock
Parallel alignment of platy minerals AND/OR alternation of light-dark minerals
process of metamorphic evolution of shale
Slate: When subjected to slight increase in temperature shale becomes slate
Low grade, temperature metamorphism
Mudstone protolith
Larger grain size
Grain size increases with temperature
Also true for igneous rocks
Distinct foliation -> slaty cleavages
Phyllite
Low-medium grade metamorphism
Clay minerals neocrystalise into mica
Fine grained, mica-rich rock
Satiny lustre
Larger grain size
Schist
Medium-high grade metamorphism
Fine to coarse grained
Larger micas
Distinct foliation occurs
Other minerals neocrystalise
Gneiss
Highest metamorphic grade
Subduction zones
Contact metamorphism
Converging plates
Banded foliation -> felsic and mafic layering
Light bands = feldspars, quartz
Dark bands = amphibole, biotite
why are some rocks not foliated? what is their name?
Non-foliated metamorphic rock = hornfel
Either occurs in absence of differential stress
New crystals are equant
From recrystallisation or neocrystallisation
Similar composition but different structure to protolith
e.g.
Hornfel
Metamorphism because of heating
Quartzites
Recrystallisation of quartz protolith
Metamorph of quartz sandstone or chert
Forms new, larger grains
Marble
Metamorphism of limestone
Recrystallisation of calcite protolith
Original fossils are destroyed or hard to recognise
what are Metamorphic grades
range of metamorphic change a rock undergoes
Low = little metamorphic change
High = significant metamorphic change
Increasing metamorphic grade
Shale: slate -> phyllite -> schist -> gneiss (all foliated)
what are Metamorphic facies
set of mineral assemblies that can be indicative of the main temperature and pressure of metamorphic conditions
Different minerals have specific ranges of temperature and pressures that it is stable/will form
How to read graph
Horizontal axis = temp
Vertical axes = pressure and depth
Increase in depth/pressure at 600°C = amphibolite -> eclogite
Increase in temperature at 4kbar = greenschist -> amphibolite
Each field/coloured section is a metamorphic facies
Each dotted line is a different geotherm at a specific tectonic location
For a given set of pressure and temperature conditions
If we determine the minerals in the metamorphic rock and its protolith
We can determine its metamorphic facies
We will know the range of temperature and pressure conditions the rock was metamorphosed
named after dominant amphibole in metamorphosed basalts
They determine the colour
E.g. greenschist has actinolite, blueschist has glaucophane, amphibolite has hornblende
what are index materials
Materials that do change stability easily are index materials
Metamorphic zones = rock in an area that consists of a very specific minerology -> characterised by specific index material
Can map metamorphic conditions over areas
Not all materials are useful in identifying metamorphic environments
E.g. quartz, feldspar -> it is stable in all conditions
Metamorphic processes
Neo crystallisation / Metamorphic reaction
Phase change
Recrystallisation
Plastic deformation
Pressure solution
Neo crystallisation / Metamorphic reaction
Growth of new minerals that are different to protolith
Chemical reaction occurs that changes chemical composition of rock = new minerals
Atoms move through solid crystal or dissolve and reprecipitate
E.g. Orthopyroxene + plagioclase = Garnet
Orthopyroxene and plagioclase react to make garnet
Reaction occurs due to increase in pressure at high temperature
Phase change
Mineral grain transforms into a new grain with the SAME chemical composition but DIFFERENT crystal structure
E.g. Quartz to Coesite
Both have same SiO2 composition
At high pressure: quartz -> coesite
Distance between atomic bonds change
Atom arrangement is different
Recrystallisation
Size and shape of grains change but composition stays the same
Recrystallised grains = New grains form in the expense of pre-existing larger grains
Pressure could squish grains and make them smaller
Occurs until rock is fully recrystalised
Same mineral between all stages
Plastic deformation
Minerals flatten or elongate without breaking
Grains deform due to load
Do not change mineral or crystal composition
Pressure solution
Rock is squeezed more strongly in one direction than others in the presence of water
Mineral where pressure is the strongest dissolve
Dissolved ions precipitate along less squeezed faces
Pressure solution causes grains to become shorter in one direction and longer in another
E.g. Oolithic limestone
what are Agents of metamorphism
Heat
Lithostatic Pressure
Temperature + pressure
Directional stress : Deformation
Protolith
effect of heat in metamorphism
Metamorphism takes place around 200-850°C
Between temperature of diagenesis and melting
Temperature increases with depth
Called geotherm
Geotherm depends on geothermal gradient
Increase in temperature = atoms in grains vibrate rapidly = stretch and bends chemical bonds
Vibrations so large = cause atoms to break bonds and form new bonds either with
New atoms within grain
New atoms in different grain -> after they migrated
Leads to neo crystallisation or recrystallisation
what is a geotherm
rate at which temperature change with depth or pressure
Different geothermal describe different rates
Depends on tectonic setting
Subduction zone vs mid ocean ridge
Subduction zones = cold geotherms
Rock moves below ground and introduces coldness from surface
Temperature increases with depth slower
Where magma forms = warm geotherm
Temperature increases with depth faster
Geotherm determines what minerals will form
Hotter geotherm = formation of higher pressure and temperature minerals
Colder geotherm = formation of lower pressure and temperature minerals
Lithostatic Pressure
pressure increases with depth -> 270/300 kbar/km
Most rocks metamorphose at 40km
put stress on grains and cause them to align in a specific direction = foliation
how to use pressure and temperature of metamorphic conditions to identify minerals
By knowing when different minerals are stable in what conditions = we can know which metamorphic conditions resulted in this rock
Use minerals like kaolinite and pyrophyllite to determine temperature conditions rocks were formed in -> narrow temperature conditions
Use kyanite or andalusite to determine pressure conditions -> narrow pressure conditions
Directional stress : Deformation
Stress applied on rock due to an external force causes it to deform
-> this determines preferred grain orientation
Change in length of one direction is different to the other
Orientation is perpendicular to maximum stress
Preferred orientation is called foliation
Horizontal force = grain lengthens in vertical direction
If direction of force is equal on all surfaces of rock -> grain shrinks but no new foliation occurs
Protolith + impact on metamorphosed rock
The chemical composition and grain texture of the original rock impacts how it metamorphoses
Final chemical composition depends on the original minerals in the protolith
Unless magma or fluids per image the rock, chemical composition of the original and final metamorphic rock should be the same
Fluids can come take away or bring new atoms
E.g. water with dissolved ions
Help crystal rearrange
Aids in change in structure and mineral composition
Type of metamorphism and tectonic setting
High-pressure metamorphism
Contact / thermal metamorphism
Regional metamorphism
High-pressure metamorphism
A long subduction zones
Rocks are transferred to great depth
Metamorphic rocks categorised by
HIGH PRESSURES
Foliation
LOW TEMPERATURE
Subduction zones are colder compared to surrounding rocks
Contact / thermal metamorphism
Take place near magmatic intrusions
-> E.g. back arc areas (volcanoes) behind subduction zones, diverging plate volcanoes, volcanic hot spots
Magma is hot
Heat is transferred
Change in heat causes atoms to rearrange and metamorphism to occur
HIGH TEMPERATURES
LOW PRESSURE
Hornfels is dominant rock
Not lots of shear/external stresses -> no foliation
Regional metamorphism
Collisional zones between two tectonic plates forming mountains called metamorphic belts
-> E.g. Alps or Himalayas
Centre of metamorphic belt = more intense metamorphic conditions
Metamorphic conditions decrease symmetrically as you go further away from belt
Rocks are being buried, deformed, exhumed
HIGH TEMPERATURE
HIGH PRESSURE
Composition and structure of rock is changed
Rock heated by geothermal gradient and plutonic magma intrusions
Rock squeezed and heated by being buried
Due to weight of new continental lithosphere that crashed to form mountains = further increased pressure
Rocks that were at surface of one continent could end up at great depths
Rock experience differential stresses when being smashed/sheared at great pressure
Lots of shearing and displacement of rock due to lots of pressure
Foliation
Shale (protolith) + regional metamorphism -> slate, phyllite, schist, gneiss, migmatite