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LIB Safety, Capacitors, Supercapacitors, Fuel Cells
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Thermal runaway failure
External heat source that can cause electrolyte to melt the system
What can cause an internal short?
Dendritic Li metal can go through the separator, causing separator failure
Most common failure runaway
Electrolyte can break down in cell, and gas can escape and combust, causing partial decomposition of cathode and burning graphite
What temperature does a separator typically melt at?
130C
Shutdown separator
At a certain temperature, all pores collapse in the separator
How does a shutdown separator work?
Since it’s a non-porous substance, no ion conductivity occurs, stopping energy release if there is a short
Ceramic coated separator, how does it differ from a shutdown separator?
Have temperature buffer to fight shorting, without shutting down the system
What is the underlying issue of why separators fail at high temperatures?
Pores collapsing - is an issue