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catabolism
energy-producing, convergent pathway that breaks down larger, complex molecules into smaller pieces
anabolism
divergent pathways use energy to build complex structures; aka biosynthesis
all chemical reactions are influenced by 2 forces:
tendency to achieve highest degree of randomness
tendency to achieve most stable bonding state
bioenergetics
quantitative study of energy transduction (changes of one form of energy into another)
ΔG
free energy; expresses amount of energy capable of doing work during a reaction at constant temperature and pressure
if ΔG’ = 0, the reaction is _________
at equilibrium
free energies of reactions are __________
additive
is ΔG a true representation of the free energy change in a reaction?
no; ΔG assumes standard conditions and doesn’t take into account the actual concentrations of reactants and products
the free energy change of a reaction is ___________ of the pathway by which the reaction occurs
independent
units for ΔG
kJ/mol
do hydrolysis reactions tend to be spontaneous/favorable or nonspontaneous/unfavorable?
strongly favorable
why is the hydrolysis of ATP favorable?
better charge separation in products, more favorable resonance stabilization of products, better solvation of products