Alkene alkyn rxn

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11 Terms

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hydrogen halide

HBR, HCl, HI

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acid catalyzed water addition

H2SO4 + H2O

H2SO4 + HgSO4+ H2O (alkynes)

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acid ctalyzed alcohol addition

H2SO4 + R-OH

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hydroboration oxidation

BH3/THF + OH, H2O2, H2O

9BBN/ethr + OH, H2O2, H2O

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halide addition

Br2, Cl2 in CH2CL2

Br2/Cl2 + H20 or R-OH

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hydrogenation

H2 + Pd/C

H2 + lindlars catalyst/poisoned catalyst

Na + NH3 (liq)

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Epoxidation

RCO=OOH

  1. MCPBA + 2. LAH + 3. H+


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oxymercuration reudction

Hg(OAc)2, H20/THF + NaBH4

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Carbene

Ch2I2 + ZNCu

CHCl3 + K+OC(CH3)3

CH (halide) + ionic structure

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Ozonolysis


O3 @ -78 degrees C + Zn, CH3CO2H

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acetylide

NaNh2 + CHx - Br