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15 Terms

1
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In Oxymercuration-Demercuration: OH goes to the (more/less) substituted carbon, whereas in hydroboration-oxidation: OH goes to the (more/less) substituted carbon

more;less

2
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highest heat of hydrogenation means the (most/least) amount of subs?

least

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addition of hydrogen (cat. metals) is (syn/anti) addition therefore (cis/trans) product

syn; cis

4
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addition of halogens (Br2 and Cl2) is (syn/anti) addition therefore (cis/trans) product

anti; trans

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hydroboration-oxidation is (syn/anti) addition therefore (cis/trans) product

syn; cis

6
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<p>allyl or vinyl</p>

allyl or vinyl

allyl

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<p>allyl or vinyl</p>

allyl or vinyl

vinyl

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formula for how many isomers:

2^n

9
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<p>What is the IUPAC name for the following compound?</p>

What is the IUPAC name for the following compound?

1-allylcyclopentene

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<p>What is the IUPAC name for the following compound?</p>

What is the IUPAC name for the following compound?

4-chlorocyclohexene

11
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Electrophilic Addition of Hydrogen Halides

HCl, HI

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Addition of water

H2O/H3O+, OH goes on the more substituted carbon, H goes on less substituted carbon

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Addition of alcohol

CH2OH,H+,

14
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Addition of HBr (2)

HBr/CH2Cl2, Br on the more substituted carbo; HBr/peroxide, anti-Mark. so Br adds to the less subed carbon

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Addition of bromine