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Second booklet
Theory of Collision
For chemical reactions to occur, particles must first collide with each other, with sufficient activation energy and in the correct orientation
Collide
Particles must first physically come into contact with each other
Sufficient Activation Energy
Particles must collide at great enough speeds to break existing chemical bonds for the reaction to occur
Correct Orientation
Particles must align in the exact direction to guarantee correct atoms make contact
Factors influencing rate of chemical reaction
Temperature, Concentration, Surface Area, Agitation, Catalyst
Temperature
When increased, kinetic energy of reactant particles also increases to meet the sufficient activation energy (increasing rate of successful collisions), further speeding up the reaction as the particles move faster
Concentration
An increase in the number of particles per unit volume decreases the distance between particles, increasing the rate of collisions and hence the reaction rate
Agitation
Stirring increases the number of reactant particles exposed to each other at the same time, further introducing collisions and speeding up the reaction rate
Surface Area
Increased spaces of contact to each other through increasing the particles (typically achieved through grinding into powders, e.g. mortar/pestle)
Catalyst
Provide an alternative lower activation energy reaction pathway without being consumed in the process, and can hence be re-used to speed up other reactions
Decomposition
Where a single reactant is broken down into two or more products (e.g. H₂O₂ → H₂O + O₂)
Neutralisation
Acid (produce Hydrogen ions in water) + Base (receives protons) → Salt + Water
React to form water and salt as the products (e.g. HCl₂₍aq₎ + NaOH₍aq₎ → NaCl₍aq₎ + H₂O
Acid + Carbonate
Need to balance equation: Acid + Carbonate → Salt + Water + Carbon dioxide
Produces salt, water and carbon dioxide (e.g. vinegar and baking soda producing CO₂ bubbles)
Acid + Hydrogencarbonate (bicarbonate)
Acid + Hydrogencarbonate → Salt + Water + Carbon dioxide
Produces salt, water and carbon dioxide (e.g. 2HCl + CaCO₃ → CaCl₂ + H₂O + CO₂)
Acid + Metal
Metal + Acid → Salt + Hydrogen gas (MASH)
Produces salt + hydrogen gas (e.g. Mg + 2HCl → MgCl₂ + H₂₍g₎ )
Precipitation
Chemical reaction in aqueous solution; two soluble ionic compounds mix to form insoluble solid product (precipitate)
Mole (chemistry)
Avorgado's constant: 6.022×10²³ particles (represents number of molecules in substance, found by multiplying atomic number)