Reaction Mechanisms

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17 Terms

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Acid-Catalyzed Hydration (alkene)

H30+ (or dilute H2SO4)

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Oxymercuration-Demurcuration

  1. Hg(OAc)2, H20

  2. NaBH4


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Hydroboration-Oxidation

  1. BH3, THF

  2. H2O2, NaOH


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Hydrohalogenation

HX

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Halohydrin Formation

X2, H2O

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Halogenation

X2

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Syn Dihydroxylation

KMnO4 or OsO4/NMO

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Anti Dihydroxylation

  1. RCO3H

  2. H3O+


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Ozonolysis

  1. O3

  2. DMS or ZN/H20


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Catalytic Hydrogenation

H2, Pt

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Epoxidation

RCO3H (MCPBA)

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Radical Addition of HBr

HBr, ROOR

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Acid Catalyzed Hydration (Alkyne)

  1. H2SO4, H20

  2. HgSO4


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Halogenation (alkyne)

X2, CCl4

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Dissolved Metal Reduction

Na (metal), NH3

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Ozonolysis (alkyne)

  1. O3

  2. H2O


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Alkylation

  1. NaNH2

  2. Halogen plus addition