Transition Metal Complex Ligands

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Vocabulary flashcards covering the names, formulas, charge states, and classifications of common transition metal complex ligands.

26 Terms

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Monodentate ligand

A ligand that binds to a metal center using only one donor atom.

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Polydentate ligand

A ligand that binds to a metal center using multiple donor atoms.

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Ambidentate ligand

A ligand (such as NO2−NO_2^- and SCN−SCN^-) that can coordinate through different atoms, where the specific name indicates which atom bonds to the metal.

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Aqua

H2OH_2O

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Ammine

NH3NH_3

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Carbonyl

COCO

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Methylamine

CH<em>3NH</em>2CH<em>3NH</em>2

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Nitrosyl

NONO

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Pyridine

C<em>5H</em>5NC<em>5H</em>5N

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Fluoro

F−F^-

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Chloro

Cl−Cl^-

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Bromo

Br−Br^-

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Iodo

I−I^-

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Oxo

O2−O^{2-}

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Hydroxo

OH−OH^-

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Cyano

CN−CN^-

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Sulfato

SO42−SO_4^{2-}

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Thiosulfato

S<em>2O</em>32−S<em>2O</em>3^{2-}

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Nitrito-N (nitro)

NO2−NO_2^-

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Nitrito-O (nitrito)

ONO−ONO^-

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Thiocyanato-S (thiocyanato)

SCN−SCN^-

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Thiocyanato-N (isothiocyanato)

NCS−NCS^-

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Ethylenediamine (en)

NH<em>2CH</em>2CH<em>2NH</em>2NH<em>2CH</em>2CH<em>2NH</em>2

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Oxalato (ox)

C<em>2O</em>42−C<em>2O</em>4^{2-}

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Ethylenediaminetetraacetato (EDTA)

C<em>10H</em>12N<em>2O</em>84−C<em>{10}H</em>{12}N<em>2O</em>8^{4-}

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Diethylenetriamine (dien)

(NH<em>2CH</em>2CH<em>2)</em>2NH(NH<em>2CH</em>2CH<em>2)</em>2NH