assumptions - isotherms and mechanisms
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7 Terms
langmuir
monolayer
homogenous surface
constant adsorption energy
localized sites
single molecule per site
no neighbouring effect
dissociative langmuir
diatomic molecule break apart upon adsorption
requires two adjacent vacant surface sites
monolayer
homogenous surface
no neighbouring effect
fixed total site density
freundlich
multilayer
heterogenous surface
empirical
non-ideal adsorption
no saturation at high pressure
exponential heat distribution
BET
multilayer
homogenous
layer formation
negligible lateral interactions
liquid-like layers
eley-rideal
direct interaction
single site coverage
no competitive adsorption
homogenous surface
reaction product desorption
unimolecular system
monolayer
homogenous surface
localised adsorption
no lateral interactions
equilibrium adsorption
single site occupancy
langmuir-hinshelwood
monolayer
heterogenous surface
reversible adsorption
negligible interactions