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A reaction is spontaneous when:
It occurs without continuous external energy input
The symbol for entropy is:
S
Entropy is best described as:
Degree of disorder
Enthalpy refers to:
Heat content of a system
A reaction with negative ΔG is:
Spontaneous
A reaction with positive ΔG is:
Nonspontaneous
Exergonic reactions:
Release free energy
Endergonic reactions:
Require energy input
A reaction is exothermic when:
ΔH is negative
A reaction is endothermic when:
ΔH is positive
The Gibbs free energy equation is:
ΔG = ΔH – TΔS
Increasing entropy generally makes reactions:
More spontaneous
Temperature affects spontaneity because it:
Multiplies the entropy term (TΔS)
A reaction with negative ΔH and positive ΔS is:
Always spontaneous
A reaction with positive ΔH and positive ΔS is spontaneous:
At high temperatures
A reaction with negative ΔH and negative ΔS is spontaneous:
At low temperatures
A reaction with positive ΔH and negative ΔS is:
Never spontaneous
Entropy increases when:
Solid becomes gas
A spontaneous reaction:
May occur slowly
Free energy is:
Energy available to do work
When ΔG = 0, the system is:
At equilibrium
Entropy of a system increases when:
Molecules become more disordered
A reaction that releases heat is:
Exothermic
A reaction that absorbs heat is:
Endothermic
Entropy is measured in:
J/mol·K
Enthalpy is measured in:
kJ/mol
A reaction becomes more spontaneous as:
ΔG decreases
A reaction with ΔG < 0 is:
Exergonic
A reaction with ΔG > 0 is
Endergonic
Entropy tends to increase when:
Molecules disperse