Alkane, Alkene, and Alkyne Reactions

0.0(0)
Studied by 0 people
call kaiCall Kai
learnLearn
examPractice Test
spaced repetitionSpaced Repetition
heart puzzleMatch
flashcardsFlashcards
GameKnowt Play
Card Sorting

1/41

flashcard set

Earn XP

Description and Tags

Organic Chemistry Reactions

42 Terms

1
New cards

H-X (excess)

markovnikov if terminal

<p>markovnikov if terminal</p>
2
New cards

H2O and acid or H3O+

markovnikov if terminal

<p>markovnikov if terminal</p>
3
New cards

  1. Hg(OAc)2, H2O

  2. NaBH4


internal

<p>internal</p>
4
New cards

  1. Hg(OAc)2, H2O

  2. NaBH4


markovnikov; terminal

<p>markovnikov; terminal</p>
5
New cards

  1. BH3, THF

  2. H2O2, NaOH, H2O


syn; internal

<p>syn; internal</p>
6
New cards

  1. BH3, THF

  2. H2O2, NaOH, H2O


anti-markovnikov; syn; terminal

<p>anti-markovnikov; syn; terminal</p>
7
New cards

X2 (excess)

anti

<p>anti</p>
8
New cards

H2, Pd/C

syn

<p>syn</p>
9
New cards

Na, NH3

anti

<p>anti</p>
10
New cards

H2, Lindlar’s catalyst

syn

<p>syn</p>
11
New cards

  1. NaNH2

  2. Primary Alkyl Halide



<p></p>
12
New cards

strong base (KOH, NaNH2) excess

anti (elimination)

<p>anti (elimination)</p>
13
New cards

H-X excess

markovnikov

<p>markovnikov</p>
14
New cards

H2O and acid or H3O+

markovnikov

<p>markovnikov</p>
15
New cards

  1. Hg(OAc)2, H2O

  2. NaBH4


markovnikov

<p>markovnikov</p>
16
New cards

  1. BH3, THF

  2. H2O2, NaOH, H2O


anti-markovnikov; syn

<p>anti-markovnikov; syn</p>
17
New cards

HBr, ROOR

anti-markovnikov

<p>anti-markovnikov</p>
18
New cards

X2

anti

<p>anti</p>
19
New cards

X2, H2O

markovnikov (oxygen); anti

<p>markovnikov (oxygen); anti</p>
20
New cards

H2, Pd/C

syn

<p>syn</p>
21
New cards

mCPBA

syn

<p>syn</p>
22
New cards

  1. mCPBA

  2. H3O+


anti

<p>anti</p>
23
New cards

OsO4, NMO

syn

<p>syn</p>
24
New cards

  1. O3

  2. Zn, H3O+ or DMS


knowt flashcard image
25
New cards

  1. Diol formation

  2. HIO4, H2O


knowt flashcard image
26
New cards

CH2I2, Zn(Cu)

syn

<p>syn</p>
27
New cards

Methyl - strong nucleophile/weak base

Sn2

28
New cards

Methyl - strong nucleophile/strong base

Sn2

29
New cards

Primary - strong nucleophile/weak base

Sn2

30
New cards

Primary - strong nucleophile/strong base

Sn2, minor E2

31
New cards

Primary - weak nucleophile/strong base

E2

32
New cards

Secondary - strong nucleophile/weak base

Sn2*/E2 at high temperature

33
New cards

Secondary - strong nucleophile/strong base

E2/minor Sn2

34
New cards

Secondary - weak nucleophile/strong base

E2

35
New cards

Tertiary - weak nucleophile/weak base

Sn1/E1 at high temperature

36
New cards

Tertiary - strong nucleophile/weak base

Sn1

37
New cards

Tertiary - strong nucleophile/strong base

E2

38
New cards

Tertiary - weak nucleophile/strong base

E2

39
New cards

Weak base/weak nucleophile

H2O, HO-R, HS-R

40
New cards

Weak base/strong nucleophile

SH-, SR-, CN-, I-, Br-, Cl-

41
New cards

Strong base/weak nucleophile

KOtBu, DBU, DBN, LDA, NaH

42
New cards

Strong base/strong nucleophile

OH-, NH2-, acetylide