Exam 1 Reagants

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Last updated 8:21 PM on 9/8/26
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8 Terms

1
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Grignard: R-X + Mg+

→ R-Mg-X

solvents: THF or Et2O

2
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Organolithium: R-X + 2Li

→ R-Li + Li-X

solvent: hexane or Et2O

3
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RMgX and RLi + Epoxides

this is because RMgX and RLi are good nucleophiles and can allow for nucleophilic ring opening!

They will attack the LESS substituated ring C and cause inversion of that C


<p>this is because RMgX and RLi are good nucleophiles and can allow for nucleophilic ring opening! </p><p>They will attack the LESS substituated ring C and cause inversion of that C</p><p></p>
4
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Gilman/ Li Diorganocopper: 2R-Li + CuI

→ R2CuLi + Li

reagants: Et2O or THF

5
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organohalogens and Gilmans: R2CuLi + R’-X

→ R-R’ + RCu + LiX

<p>→ R-R’ + RCu + LiX</p>
6
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dichlorocarbene

:CCl2

7
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dichlorocarbene to alkenes

solvents: CH3Cl and Ko-t-Bu

<p>solvents: CH3Cl and Ko-t-Bu</p>
8
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Simmons Smith

alkene + CH2I2 —ZnCu and Et2O → opening alkene

<p>alkene + CH2I2 —ZnCu and Et2O → opening alkene</p>