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New Mineral Nutrition
Mineral
An inorganic element acquired mostly in the form of inorganic ions from the soil
Nutrients
A substance needed to survive or necessary for the synthesis of organic compounds
Mineral nutrition
the process by which plants absorb and utilize essential inorganic elements from the soil for growth and metabolism
Essential nutrients
elements a plant requires; there are 17 of them, derived from water, air and soil
Beneficial nutrients
promote plant growth but are not necessary to complete the life cycle
Arnon and Stout
proposed the three criteria for essentiality
Essential for life cycle, Specific, irreplaceable function, Direct metabolic role
Three Criteria for Essentiality
Essential for life cycle
a deficiency makes it impossible for the plant to complete its vegetative or reproductive stage
Specific, irreplaceable function
the deficiency is specific to that element and can be prevented or corrected only by supplying it
Direct metabolic role
the element is directly involved in the nutrition of the plant
Macronutrients (9)
needed in large quantities (more than 10 mmole/kg dry matter)
Micronutrients (8)
needed in small quantities (less than 10 mmole/kg, or less than 50 ppm)
Non-mineral nutrients
C, H, O; generally available through air and water
Primary macronutrients
N, P, K; deficiencies are more common but can be corrected with fertilizers
Secondary macronutrients
Ca, Mg, S
Trace elements
another name for micronutrients
Carbon, Hydrogen, Oxygen, Nitrogen, Phosphorus, Pota, Calcium, Magnesium, Sulfur
The 9 Macronutrients Elements
Iron, Boron, Zinc, Copper, Manganese, Molybdenum, Chlorine, and Nickel
The 8 Micronutrients Elements
Carbon
taken in as CO₂ from the atmosphere
Oxygen
absorbed in molecular form from air or water; also generated within the plant during photosynthesis
Hydrogen
released from water during photosynthesis
Nitrogen
absorbed from the soil as nitrate or ammonium; some bacteria and cyanobacteria can fix N from the air directly
mineral elements
absorbed from the soil as ions; derived from weathering of rocks
Carbon
forms the backbone of most plant biomolecules (proteins, starches, cellulose)
Oxygen
required for aerobic cellular respiration to break down glucose and produce ATP
Hydrogen
builds sugars; H⁺ is needed for the proton gradient that drives the ETC in respiration and photosynthesis
Nitrogen
synthesis of amino acids, proteins, nucleic acids, vitamins, hormones, coenzymes, ATP and chlorophyll; needed especially in meristematic tissues
Potassium
activates enzymes; K⁺/Na⁺ pump and active transport; anion-cation balance; opens and closes stomata; helps turgidity of cells (common in cell sap of vacuole)
Phosphorus
synthesis of nucleic acids, phospholipids, ATP, NAD and NADP; part of the cell membrane and some proteins
Magnesium
part of the chlorophyll molecule (its central atom); activates enzymes of phosphate metabolism; DNA and RNA synthesis; binding of ribosome subunits
Sulfur
constituent of cysteine and methionine and some proteins; present in coenzyme A, thiamine, biotin and ferredoxin
Iron
synthesis of chlorophyll; constituent of ferredoxin and cytochromes; activates catalase
Manganese
activates enzymes of photosynthesis, respiration and N₂ metabolism; electron donor for chlorophyll b; decarboxylation in respiration
Molybdenum
required for nitrogen fixation; activates nitrate reductase
Boron
increases uptake of water and calcium; meristem activity and pollen tube growth; translocation of carbohydrates
Copper
component of oxidase enzymes and plastocyanin; electron transport in photosynthesis
Zinc
component of indoleacetic acid (a plant hormone); activates dehydrogenases and carboxylases; present in carbonic anhydrase
Chlorine
water-splitting reaction leading to O₂ evolution in photosynthesis; anion-cation balance
Calcium
forms calcium pectate in the middle lamella of cell walls; activates enzymes for root and shoot tip growth; needed for cell division and enlargement
K⁺ pumped into guard cells
water potential decreases inside, water moves in, cells become turgid and the stomata open
K⁺ pumped out of guard cells
water potential increases inside, water moves out, cells become flaccid and the stomata close
Aluminum, Cobalt, Lithium, Silicon, Sodium
Beneficial Elements
Aluminum
increased antioxidant properties and growth
Cobalt
involved in N-fixation by legumes; increases growth, nodule number and weight, and pod yield and quality (peanut example: best result with seed treatment plus foliar sprays)
Lithium
enhances transport of sugars from leaves to roots in certain plants; increases chlorophyll content
Silicon
taken up as silicate; strengthens cereal stems to resist lodging; thickens and strengthens cell walls
Sodium
taken up as Na⁺; can partly replace K for some crops
Nutritional disorder
caused by a nutrient deficiency or toxicity
Deficiency symptoms
appear when minerals are not available to plants
Toxicity symptoms
appear when minerals are in excess
Mobile elements
move to new growth areas, so deficiency symptoms show first in older leaves (N, P, K, Mg, Cl, Na, Zn, Mo)
Immobile elements
do not move to new growth, so deficiency symptoms show first in new growth (Ca, S, Fe, B, Cu)
Corrective measures
agronomic methods (fertilizer, crop rotation, Integrated Nutrient Management, cover cropping), soil improvement (soil testing, organic amendments, biofertilizers), varietal improvement (breeding for root architecture, GMO)
Nitrogen
yellowing starting at the tip and spreading along the midrib; old leaves light green and chlorotic at the tip; stunted plants; corn shows yellow or brown midribs
Phosphorus
reddish-purple leaves (especially young plants); stunted growth; brown necrotic tips; older rice leaves orange or purplish
Potassium
“firing” (drying) along the tips and edges of lowest leaves; stunted, easily lodged plants; brown spots on rice often mistaken for disease; green “arrow” shape in barley
Magnesium
whitish stripes along veins and purplish undersides of lower leaves; reddening or browning of leaf tips and margins in corn; chlorosis on the flag leaf of rice
Calcium
chlorotic-white leaf tips and drying of growing points; new leaves curl and edges turn necrotic and scorched
Sulfur
chlorotic-white leaf tips and drying of growing points; new leaves curl and edges turn necrotic and scorched
Iron
yellowing on young leaves while older leaves stay normal; green veins fade to pale yellow if it persists
Manganese
pale grayish-green or pale yellow interveinal chlorosis on young leaves
Zinc
white band on corn leaves with green midrib and margins; dusty brown spots on rice; small necrotic spots on wheat
Boron
young leaves become brittle, twisted, with wrinkled tips
Copper
rice leaves do not unroll and tips look needle-like; corn leaves spiral with a bluish-green tint
Molybdenum
pale leaves that may be scorched, cupped or rolled; thick, brittle leaves that wither leaving only the midrib
Chlorine
chlorotic and necrotic spotting with abrupt boundaries between dead and live tissue; often misdiagnosed as physiological leaf spot
Herbicide damage
burned tips and edges, whitecap leaves
Drought stress
grayish-green color and leaves rolling up to the size of a pencil
Helminthosporium blight
small spots that gradually spread across the leaf (a fungus; saprophyte on dead tissue)
Healthy leaf
dark green due to high chlorophyll
Nitrogen
dark green plants, succulent new growth, susceptible to disease and insects, easy lodging under drought, blossom abortion and lack of fruit set
Phosphorus
no direct effect, but shows deficiencies of Zn, Fe and Mn; may interfere with Ca nutrition
Potassium
shows Mg and possibly Ca deficiency due to cation imbalance
Calcium
may show Mg deficiency and, in high excess, K deficiency
Magnesium
cation imbalance showing signs of Ca or K deficiency
Sulfur
premature senescence of leaves
Boron
leaf tips and margins turn brown and die
Copper
Fe deficiency may be induced, very slow growth, stunted roots
Iron
bronzing and tiny brown spots on leaves
Manganese
brown spots surrounded by a chlorotic zone and circle on older leaves
Molybdenum
not of common occurrence
Zinc
Fe deficiency develops
4Rs framework
Right Source, Right Place, Right Time, Right Rate (for greatest fertilizer nutrient use efficiency)
Right source
matches fertilizer type to crop needs
Right place
keeps nutrients where crops can use them
Right time
makes nutrients available when crops need them
Right rate
matches the amount of fertilizer to crop needs