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What five factors guide chemical synthesis design?
Supply, conditions, yield/purity, uses, impacts.
What is the Haber process equation?
N₂(g) + 3H₂(g) ⇌ 2NH₃(g)
What is the enthalpy change for the Haber process?
ΔH = −92 kJ mol⁻¹
Where do the reagents (N and H) for the Haber process come from?
Nitrogen from air and hydrogen usually from natural gas.
What is the steam reforming reaction for hydrogen production?
CH₄ + H₂O ⇌ CO + 3H₂.
What makes a suitable reagent supply?
Available, affordable, reliable.
What conditions does the Haber process use?
About 450°C, 200 atm, iron catalyst.
Why does low temperature favor ammonia production?
Cooling favors the heat-producing direction.
Why is 450°C used in the Haber process?
It balances equilibrium yield with a commercially useful reaction rate.
Why does high pressure favor ammonia production?
Four gas moles become two, favoring fewer gas particles.
What are the risks of using higher pressure in the Haber process?
More energy, stronger equipment, and greater risk.
What does the iron catalyst change in the Haber process?
It changes the speed, not the equilibrium yield.
How do yield and purity differ?
Yield is how much you obtained; purity is how clean the sample is.
What are the formulas for yield and purity?
Yield: actual ÷ theoretical × 100; Purity: desired substance's mass ÷ sample's total mass × 100.
How is ammonia separated from the reaction mixture?
Cool, condense, collect.
Why recycle unreacted gases in the Haber process?
Reuse reagents for more product overall, reducing waste and cost.
What is the purification trade-off in chemical synthesis?
Cleaner product costs more due to time, energy, and equipment.
What are the main environmental concerns of the Haber process?
CO₂ emissions from production and fertilizer runoff.
What economic costs are important in chemical synthesis?
Materials, energy, equipment, workers, and waste treatment.
How does the product's use affect its synthesis?
Use sets the required purity, safety, scale, and price.
What are ammonia's social benefits and risks?
Benefits: food production and jobs; Risks: toxic leaks and polluted water.
What is the overall evaluation of the Haber process?
A compromise between yield, speed, cost, and safety.