Organich chemistry: Alkene reactions

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Description and Tags

Addition rxns

9 Terms

1
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Hydrohalogenation (H-X)

H-X (Br, Cl, I)

2
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hydrohalogenation w/ peroxide (H-X w/ ROOR)

H-X w/ ROOR/Ch3OOCH3/H20

3
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Acid-catalyzed hydration (H & OH)

dilute H2SO4 (aka H2SO4,H2O or H3O+)

4
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Oxymercuration-demercuration (H & OH)

1. Hg(OAc),H2O, 2. NaBH4

5
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Hydroboration-Oxydation (H & OH)

Alkene vs 1.BH3 . THF 2. NaOH, H2o2

6
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Catalytic Hydrogenation (H & H)

H2 and metal catalyst (Ni,Pd,Pt)

7
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Halogenation (X & X)

Cl2 or Br2

8
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Halohydrin Synthesis (X & OR)

Cl2/Br2 and polar protic solvent (HOR)

9
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Syn-Dihydroxylation (OH & OH)

1. OsO4, 2. NaSO3