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acetic acid
corrosive enough to cause serious acid burns on skin; vapors irritate eyes and nasal passages.
acetone
not very toxic; flammable
benzene
serious carcinogenic hazard: damages bone marrow, causes various blood disorders, may lead to leukemia, poisons liver and kidneys; flammable; toluene as substitue
carbon tetrachloride
serious liver and kidney damage, skin irritation, death by respiratory failure (if high concentrations), suspected carcinogenic material; non flammable
chloroform
similar toxicity to carbon tetrachloride; suspected carcinogen; methylene chloride as substitute
(carbon tetrachloride - serious liver and kidney damage, skin irritation, death by respiratory failure (if high concentrations), suspected carcinogenic material; non flammable)
1,2-Dimethoxyethane
flammable; explosive peroxide formation; reproductive toxin
(miscible with water = useful alternative to solvents like dioxane and tetrahydrofuran)
dioxane
suspected as carcinogenic; toxic affecting CNS, liver, kidneys, skin, lungs, and mucous membranes; flammable; explosive peroxide formation
ethanol
intoxicant; flammable
ether (diethyl ether)
most flammable solvent in lab (dense vapors travel long distances); not very toxic (drowsiness, nausea if high concentration); highly explosive peroxides
hexane
most serious hazard = flammability; skin and respiratory tract irritation; intoxicant and depressant of CNS
Ligroin
see hexane
methanol
ethanol hazards apply but more toxic; ingestion can cause blindness and death; more volatile = more fire danger
methylene chloride (dichloromethane)
not flammable or serious carcinogen; liver damage if ingested; vapors cause drowsiness or nausea
pentane
see hexane
petroleum ether
see hexane
pyridine
some fire hazard; highly toxic (depress CNS, irritate skin and respiratory tract, damage liver, kidneys, gastrointestinal system, cause temporary sterility)
tetrahydrofuran
irritation of skin, eyes, respiratory tract; explosive peroxides; flammable
toluene
not carcinogen but at least as toxic as benzene; anesthetic; damage CNS; flammable
solvents not used in lab because of carcinogenic properties:
benzene, carbon tetrachloride, chloroform, and dioxane