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Polarity
Nonpolar (due to nonpolar C–C and C–H bonds)
Intermolecular Forces
Weak dispersion forces only
Solubility
Immiscible in water and hydrophobic ("water-fearing").
Boiling Points
Lower boiling points than polar molecules of similar mass; boiling points increase with chain length/surface area
Saturated Hydrocarbons
Alkanes (Cn H2n+2); contain maximum hydrogens per carbon with single bonds only.
Unsaturated Hydrocarbons
Alkenes, Alkynes, and Aromatics; contain double or triple bonds and fewer than 2n+2 hydrogens
Rule
Each double bond or ring reduces hydrogen count by 2; each triple bond reduces hydrogen count by 4