1/14
hmm....
rate of reaction
the speed at which a chemical reaction takes place (ex. change in concentration of a reactant/product per unit time)
steric effect
3d shape, orientation, and size of colliding molecules affect how particles approach and react to one another (affects reaction rate)
activation energy
minimum amount of energy a reactant must have for a collision to be effective
maxwell-boltzmann distribution
describes distribution of KE among particles in an ideal gas at a given temperature. shows how molecular speeds vary and provides insight into how temperature affects reaction rates
enzymes
biological catalysts that speed up chemical reactions in living organisms
substrate
a substance acted upon by an enzyme at its active site
active site
the region on the surface of an enzyme molecule that binds the substrate molecule
reaction mechanism
a series of elementary steps by which a chemical reaction occurs
elementary steps
a reaction with no intermediates; a reaction that takes place in a single step with a single transition state (most commonly unimolecular or bimolecular)
intermediate
a species which is not a reactant or a product but which is formed in one stpe of a reaction and used up in the next
rate determining step (RDS)
the slowest elementary step in a chemical reaction that involves a number of elementary steps
order
shows how the concentration of a chemical, typically a reactant, affects the rate of reaction
transition state
point at which new bonds are being formed and old bonds are being broken
pseudo-first-order reaction
a second order reaction that is made to behave like a first order reaction
collision theory
for a reaction to occur particles must collide in the correct orientation with E > Ea