1/12
Looks like no tags are added yet.
Hydrohalogenation.
H-BR, H-Cl, H-I
Mark, non stereo, can rearrange
Halogenation
Reagents: Br₂ or Cl₂ in an inert solvent
non regio and anti addition
4. Halohydrin formation
Reagents: Br₂/H₂O or Cl₂/H₂O
regio, OH on more sub Carbon, anti addition
Acid-catalyzed hydration
Reagents: H₂O/H₂SO₄ or H₃O⁺
Forms: Alcohol.
mark, non stero, rearrangement possible
Oxymercuration–reduction
Reagents: 1. Hg(OAc)₂, H₂O 2. NaBH₄
Forms: Alcohol.
mark and anti addition
Hydroboration–oxidation
Reagents: 1. BH₃·THF 2. H₂O₂, NaOH
Forms: Alcohol.
anti mark and syn addition
Dihydroxylation
Reagents: 1. OsO₄ 2.NMO
Forms: Vicinal diol—two OH groups on adjacent carbons.
non regio and syn addition
Epoxidation
Reagents: mCPBA or another peroxyacid, RCO₃H
Forms: Epoxide—a three-membered ring containing oxygen.
non regio
Ozonolysis
Reagents: 1. O₃ 2. (CH3)2S or Zn/ AcOH
Forms: Aldehydes and/or ketones by cutting the C=C and putting C=O at each former alkene carbon
Periodic acid cleavage
Reagents: HIO₄
Forms: Aldehydes and/or ketones by cutting the C–C bond between adjacent OH-bearing carbons.
2 alcohols on next to carbons
Hydrogenation
Reagents: H₂ with Pd/C, Pt, or Ni
Forms: Alkane.
non regio, syn addition