CHEM 3411 Exam 4 Reaction

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12 Terms

1
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Hydrohalogenation

Reagent: HX (X is a Halogen)

Product(s): Alkyl Halide
Regiochemistry: Markovnikov

Sterochemistry: N/A

2
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Hydrohalogenation with peroxide

Reagent: HX (X is a Halogen)

Product(s): Alkyl Halide
Regiochemistry: Anti-Markovnikov

Sterochemistry: N/A

3
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Acid Catalyzed Hydration

Reagent: H3O+ or dilute H2SO4

Product(s): H and OH addition
Regiochemistry: Markovnikov

Sterochemistry: N/A

4
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Oxymercuration-Demercuration

Reagent: 1) Hg(OAc)2, NucH 2) NaBH4

Product(s): H and OH addition
Regiochemistry: Markovnikov

Sterochemistry: Anti

5
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Hydroboration-Oxidation

Reagent: 1)BH3, THF 2) H2O2, NaOH

Product(s): H and OH addition
Regiochemistry: Anti-Markovnikov

Sterochemistry: Syn

6
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Catalytic Hydrogenation

Reagent: H2, Pt

Product(s): Alkane
Regiochemistry: N/A

Sterochemistry: Syn

7
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Halogenation

Reagent: X2 (X is a Halogen)

Product(s): Dihalide
Regiochemistry: N/A

Sterochemistry: Anti

8
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Halohydrin Formation

Reagent: X2, H2O

Product(s): X and OH addition
Regiochemistry: OH on more substituted

Sterochemistry: Anti

9
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Syn Dihydroxylation

Reagent: 1) OsO4 2) NaHSO3 OR cold KMnO4, NaOH

Product(s): Diol (OH + OH)
Regiochemistry: N/A

Sterochemistry: Syn

10
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Epoxidation

Reagent: mCPBA

Product(s): Epoxide
Regiochemistry: N/A

Sterochemistry: sterospecific

11
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Anti Dihydroxylation

Reagent: 1)mCPBA 2) H3O+

Product(s): OH + OH
Regiochemistry: N/A

Sterochemistry: Anti

12
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Ozzonolysis

Reagent: 1) O3 2) DMS

Product(s): Aldehyde or Ketone
Regiochemistry: N/A

Sterochemistry: N/A