Bases and Nucleophiles Orgo Exam 3

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25 Terms

1
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I-

Strong Nucleophile

Weak Base because Halogens come from strong acids

2
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Br-

Strong Nucleophile

Weak Base because Halogens come from strong acids

3
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Cl-

Strong Nucleophile

Weak Base because Halogens come from strong acids

4
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HS-

Strong Nucleophile

Weak Base

5
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HO-

Strong Nucleophile

Strong Base

6
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RS-

Strong Nucleophile

Weak Base

7
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RO-

Strong Nucleophile

Strong Base

8
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NC-

Strong Nucleophile

9
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H2O

Weak nucleophile

Weak Base

10
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ROH

Weak Nucleophile

Weak Base

11
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N3-

Strong Nucleophile

Weak Base

12
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OEt-

Strong base

Nucleophile

13
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t-BuOK

t-BuOK

Strong Base (Bulky)

Weak Nucleophile

14
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diisopropylamine

diisopropylamine

Strong Base

Weak Nucleophile

15
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LDA: lithium diisopropylamine

LDA: lithium diisopropylamine

Strong Base (bulky)

Weak Nucleophile

16
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triethylamine

triethylamine

Strong base (bulky)

Weak Nucleophile

17
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DBU

DBU

Strong Base (bulky)

Weak Nucleophile

18
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DBN

DBN

Strong Base (bulky)

Weak Nucleophile

19
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NaOH

Strong Base

Weak Nucleophile

20
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Cl-

Strong Nucleophile

Weak Base because Halogens come from strong acids

21
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H-

Strong base

Weak Nucleophile

22
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COOH-

Strong nucleophile

Weak base

23
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RSH

Strong nucleophile

Weak Base

24
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H2S

Strong Nucleophile

Weak Base

25
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F-

Weak Nucleophile

Weak base