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LECTURE 6, LECTURE 7
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growth of a black smoker chimney stage 1
Hot, Ca-rich vent fluid mixes turbulently with cold, sulphate and Ca-rich seawater
result: precipitation of a ring of Calcium Sulphate (Anhydrite) –due to the inverse solubility behaviour of Anhydrite
Metals carried in the hot fluid also rapidly precipitate -as sulphides and oxides -during the mixing process, forming a plume of dark particles above the vent
growth of a black smoker chimney stage 2
Chalcopyrite begins to precipitate and plate the inner wall of the Anhydrite chimney
mixing of seawater and hydrothermal fluid components across the porous wall by advection and diffusion
result: the deposition of Sphalerite, Chalcopyrite and Pyrite in the interstices of the wall
gradually makes the chimney less porous and more metal-rich
schematic of the active TAG hydrothermal mound
hydrothermal fluid rises rapidly, exiting the mound at the black smoker complex
cold Ca and SO4- rich seawater is entrained into the mound and mixes with hydrothermal fluid
mixing causes anhydrite, pyrite and chalcopyrite to precipitate inside the mound- increasing the acidity of the saline hydrothermal fluid
Zn dissolve in this acidic fluid and are carried by the white smoker fluid to the edges of the mound. here cooler temperatures within white smoker chimney walls causes precipitation of sphalerite and other minerals
mixing of cold Ca and SO4- rich seawater and hydrothermal fluid causes what minerals to precipitate inside a TAG hydrothermal mound?
anhydrite, pyrite, and chalcopyrite
major features of a submarine hydrothermal field at a mid-ocean ridge

chloritization of basalt is associated with
the underlying feeder zone of the mound

fast spreading centre
>10cm/yr
host sequences volcanic-dominated
more rapid heat dissipation
smaller, more numerous VMS deposits
(EPR) east pacific rise
slow spreading centre
~1-6cm/yr
deeper faulting, deeper fluid circulation
less rapid heat dissipation
larger VMS deposits
intrusive rocks in near surface
the “rose bowl” vest site on the Galapagos rift
concave, ring-shaped, and ~10m in diameter
a more passive hydrothermal system which formed as a more active system waned
shows that not all submarine hydrothermal emanations are as dramatic as the “black smoker'“ fields or zones of active eruption
where are the 7 brine pools that contain metalliferous sediments located?
where ENE trending fractures and transform faults intersect the ridge axis
atlantis II deep
14 km long and 5km wide at 2000m water depth
5km3 of densely stratified brine comprises 2 layers:
lower brine 150m thick T>60 deg C
upper brine 50m thick T>50 deg C
below the lower brine are metalliferous sediments resting on basalt
what is below the lower brine of Atlantis II deep?
metalliferous sediments resting on basalt
metalliferous sediments in Atlantis II deep appear to have precipitated from fluid at what temp?
>200 deg C
red sea brine pools
convective hydrothermal system related to rifting and driven by magmatic heat
Hydrothermal fluids predominantly derive from very saline connate fluids rather than seawater
fluids are discharged in an environment where the sulphides and oxides precipitated are stable and stratified over a widely dispersed area
enhances their potential to create extremely large metallic ore deposits
modern analogue for SEDEX (Sedimentary Exhalative Massive Sulphide)
how are red sea brine pools different from MOR setting?
Hydrothermal fluids predominantly derive from very saline connate fluids rather than seawater
fluids are discharged in an environment where the sulphides and oxides precipitated are stable and stratified over a widely dispersed area
cyprus-type VMS deposits
host basalts are typically pillowed and tholeiitic
mineralization comprises pyrite and chalcopyrite with lesser sphalerite
ore is associated with zones of intense chloritization and silicification of host rock
overlying pelagic sediments (shales and cherts) are Fe- and Mn- rich (umber)
some deposits capped by a Mn-poor Fe-rich oxidized layer (ochre)
ophiolites
a section of MOR subsequently preserved by obduction onto continental crust
characterized by sheeted gabbroic dykes, pillow basalts, and overlying pelagic sediments
basic structure of the oceanic crust
layer 1- sediments
layer 2- basaltic pillow lavas
sheeted dykes
layer 3- gabbroic rocks, fossilized magma chamber
MOHO
Mantle- peridotites, mantle