orgo alkene reactions

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8 Terms

1
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hydrohalogenation

Reagents? HX

What is added? H and X

Regiochem? X on more substituted

Sterochem? Mix of same and opposite side

2
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radical HBr addition

Reagents? HBr, ROOR light

What is added? H and Br

Regiochem? anti-markovnikov

Sterochem? syn and anti

3
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acid catalyzed hydration

Reagents? H2O and H2SO4

What is added? H and OH

Regiochem? markovnikov

Sterochem? anti and syn

4
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halohydration

Reagents? H2O and X2

What is added? X and OH

Regiochem? OH on more substituted

Sterochem? anti

5
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hydroboration

Reagents? 1) BH3
2) NaOH, H2O2

What is added? H and OH

Regiochem? anti markovnikov

Stereochem? syn

6
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X2 addition

Reagents? X2

What is added? X and X

Stereochem? opposite side

7
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catalytic hydrogenation

Reagents? H2, Pt or Pd or Ni

What is added? H and H

Stereochem? syn

8
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mercuric acetate reduction

Reagents? 1) Hg(OAc)2
2) NaBH4

What is added? H and OH

Regiochem? OH on more substituted

Stereochem? Mix of same and opposite side