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Engineering Stress
The load applied to a material divided by its original cross-sectional area, representing how much force a material experiences per unit area.
Engineering Strain
the measure of deformation representing the displacement between particles in a material body. It is calculated as the change in length divided by the original length.
Poisson’s Ration
is the ratio of transverse strain to axial strain in a material when it is subjected to axial loads, reflecting the tendency of material to expand in directions perpendicular to the applied load.
Yield Strength
The maximum stress a material can withstand before it begins to deform plastically, indicating the point at which permanent deformation occurs.
Ultimate Yield Strength
the maximum stress a material can withstand before failure occurs, beyond which it cannot return to its original shape.
Stiffness
is the resistance of an elastic body to deformation when subjected to an applied force, often measured as the ratio of applied load to displacement.
Hardness
is a measure of a material's resistance to localized plastic deformation (e.g., indentation or scratching). It indicates the material's ability to withstand wear and abrasion.
Tensile Toughness
is the ability of a material to absorb energy and plastically deform without fracturing, often measured as the area under the stress-strain curve.
Impact Toughness
is the ability of a material to withstand a suddenly applied load or shock without fracturing, usually assessed through impact testing methods.
Fracture Toughness
is a material's ability to resist crack propagation when subjected to stress, often measured by the critical stress intensity factor.
Elastic/Shear Modulus
Slope in linear part on stress strain or shear stress strain curve
Yield Strength
The maximum stress a material can withstand before it begins to deform plastically, indicating the point at which permanent deformation occurs.
Ultimate Tensile Strength
The maximum stress a material can withstand while being stretched or pulled before necking and fracture occur, corresponding to the highest point on the engineering stress-strain curve.
Elastic Deformation
Reversible deformation; returns to original shape when load is removed
Plastic Deformation
A permanent and irreversible change in the shape or dimensions of a material that persists after the applied load is removed.
Strain Hardening
The increase in strength and hardness of a ductile material resulting from plastic deformation, driven by dislocation generation and accumulation within the crystal structure.
Necking
a phenomenon in a tensile test where a material begins to narrow significantly in one localized region as it is stretched.
Breaking
the point when a material separates into two or more pieces because it can no longer withstand the applied load.
Modulus of Resilience
the maximum amount of energy per unit volume a material can absorb without undergoing permanent deformation.
Tensile Toughness
the amount of energy per unit volume a material can absorb before it fractures (breaks).
%Elongation
how much a material's length increases before fracture, expressed as a percentage of its original length. It is a measure of ductility.
Ceramic Properties
Strength: Often high in compression, but relatively weak in tension compared with their compressive strength.
Stiffness: Generally high.
Ductility: Very low at room temperature.
Toughness: Generally low fracture toughness compared with metals.
Hardness: Often very high; good wear resistance.
Conductivity: Usually poor electrical conductivity, although some ceramics are conductive.
Polymer Properties
Strength: Often lower than metals and structural ceramics.
Stiffness: Generally low.
Ductility: Highly variable; some polymers stretch considerably, while others are brittle.
Toughness: Varies significantly with polymer type and temperature.
Hardness: Generally lower than metals and ceramics.
Conductivity: Usually poor electrical and thermal conductivity.
Metal Properties
Strength: Moderate to very high, depending on alloy and processing.
Stiffness: Generally high.
Ductility: Often high; can plastically deform before fracture.
Toughness: Often good because metals can absorb energy through plastic deformation.
Hardness: Varies widely; can be increased through heat treatment or work hardening.
Conductivity: Generally good electrical and thermal conductivity.
Effects of temperature increase on mechanical properties
Yield strength, elastic modulus, tensile strength decrease; ductility increases
Effects of increased strain rate on mechanical properties
Yield strength increases, modulus of elasticity changes slightly, ductility decreases, and tensile strength usually increases
Ductile to Brittle Transition Temperature
the temperature below which certain materials change from behaving in a ductile manner to behaving in a brittle manner.
How does DBTT happen?
As temperature decreases, dislocation motion becomes more difficult in certain metals. The material has a harder time deforming plastically to relieve stress.
Consequently, a crack may propagate before significant plastic deformation can occur, causing brittle fracture.
What kind of materials does DBTT affect?
BCC and FCC metals, ceramics, and polymers
Tensile Test
Measures strength, stiffness, and ductility
Impact Test
Measures impact energy and toughness
Bending Test
Measures flexural strength and stiffness
Hardness test
Measures resistance to deformation
Nanoindentation tests
Measures hardness and stiffness at a tiny scale
How do various factors affect fracture?
Higher temp = more ductile, less brittle; faster loading = more likely to cause brittle fracture; easier to fracture with larger flaw sizes; larger sample size is more likely to contain a crazy flaw; higher ductility = more stretching before breaking; smaller grain size = usually tougher
Ductile Fracture
Lots of deformation before breaking; often forms a cup-and-cone shape.
Brittle Fracture
Little or no deformation; breaks suddenly with a flat surface.
Fatigue Fracture
Caused by repeated loading; cracks grow over time, often with beach marks.
What happens during ductile fracture?
Voids form, grow, and join together.
What happens during brittle fracture?
Bonds break with little plastic deformation.
What happens during fatigue fracture?
A crack starts and slowly grows with repeated loading until the material breaks.
Transgranular Fracture
Crack travels through the grains
Intergranular Fracture
Crack travels along grain boundaries
Ceramics During Fracture
Usually experience brittle fracture
Polymers During Fracture
Depends on temperature, loading rate, chemical bonds, etc
Metals During Fracture
Usually Ductile Fracture
Weibull Distribution
Probability of fracture vs applied stress
Weibull Modulus
Measures fracture strength variability in a material; metals generally have higher Weibull modulus than ceramics
Fatigue
Lowering of strength due to cyclic loading
Creep
Time dependent deformation under a constant load; usually happens at higher temperatures
Thermoplatsics
Linear or branched molecules
– Weak van der Waals between chains
– Exhibit ductile, plastic behavior
– Amorphous or crystalline
– Soften and melt upon heating
– Easily recycled, e.g. polyethylene (PE)
Themosets
Cross-linked or 3D network structure
– Stronger but more brittle than thermoplastics
– Decompose upon heating, as opposed to melt
– Difficult to recycle, e.g., polyurethane (PU)
Elastomers
Coil like molecules
– Linear, branched with occasional cross-links
– Sustain large elastic deformation >200%
– e.g. natural rubber
Degree of Polymerization
Tensile strength, creep resistance, melting
temperature, and impact and wear toughness
generally increase with increasing degree of
polymerization
Effect of Side Groups in Polymerization
Replacing the hydrogen atoms in polymer chains
with others (e.g., Cl, Fl) increases polarity and
leads to inter-chain hydrogen bonding
– Results in higher strengths, stiffness, and
melting temperatures
– Examples include vinyl and vinylidene polymers
Crystallization
Amorphous —> crystalline
polymer
• Higher crystallinity —> density, mechanical
strength, chemical resistance increase
• Deformation (and sometimes temperature or
electric field) can lead to crystallization
(alignment of molecular chains)
Rubbery and Leathery Polymer State
Slightly below Tm (rubbery state):
– Under —> elastic and plastic deformation
• Well below Tm, (leathery behavior)
– Lower temperature —> bonding is stronger (stiffer
polymer)
Glassy Polymer State
T < Tg, linear amorphous
polymer
• Stiff, hard, brittle
Elastic Deformation of Thermoplastics
Mostly non-Newtonian, viscoelastic behavior
– Deformation is rate-dependent
• Two deformation mechanisms for the elastic part
(1) Stretch and distort covalent bonds elongate chain
elastically
Recovery is instantaneous
(2) Distort segments of
polymer chains
Recovery over a long
period of time
Plastic Deformation of Thermoplastics
Permanent deformation
• Indicated by a stress drop beyond yield point
• Chain will stretch, rotate, slide or disentangle
• Necking – continued
sliding of the chains
in necking region
• When chains are
nearly parallel,
greater stress to
deform
• Stable necking
Stress Relaxation
stress decreases with time at constant strain
Strain Hardening In Cold Working
Increases strength and hardness but decreases ductility because increasing dislocation density makes further dislocation movement more difficult.
Bauschinger Effect
Prior plastic deformation reduces the yield stress when the loading direction is reversed.
Percent Cold Work
Measures how much a material’s cross-sectional area has been reduced during cold working
Sheet Texture in Cold Working
Crystallographic orientation of grains; think of rolling pizza dough
Residual Stresses
Internal stresses that remain without loading; compressive is usually good, tensile not so much; annealing can be used to remove these
Pros of Cold Working
Strengthen metal while producing desired shape
• Excellent dimensional tolerances and surface finishes
• Relatively inexpensive
Cons of Cold Working
Some metals brittle at room temperature (HCP)
• Ductility, electrical conductivity, and corrosion resistance
impaired by cold working
• Cannot use this for materials that will be used at high
temperatures during service
Annealing During Cold Working
Heat, hold and allow microstructures to change, and let that thing slowly cool
Hot Working
Plastically deforming a material above the recrystallization temperature; material does not strengthen during this process
Hot Working Pros
Easier to shape
• Eliminate imperfections (e.g., dislocations)
Hot Working Cons
Anisotropic behavior due to various cool
rates
• Poor surface finish and dimensional
accuracy
Homogenous Nucleation
Cool below freezing temperature – free
energy of solid is smaller than liquid.
• Create more surface between solid and liquid.
Heterogeneous Nucleation
Impurities in the liquid
• Less undercooling is needed
• Big radius of curvature with little solid/liquid
contact area
Inoculation
adding small particles to promote
nucleation → smaller grains and higher
strength
Dispersion Strengthening
adding fine particles
to form a second phase (solid state
transformation) → higher strength
Metallic Glasses
fast cooling to prevent
nucleation of crystalline structure → amorphous
Planar Growth
Smooth, flat interface.
Solid grows in a uniform front.
Occurs when the interface is stable.
Less irregular microstructure.
Dendritic Growth
Tree-like, branching crystals form.
Occurs when the interface becomes unstable.
Common in metal alloys.
Can cause uneven distribution of alloying elements (segregation).
Columnar Grains During Casting
Anisotropic properties
Equiaxed Grains During Casting
Isotropic properties
Solidification Defects
Shrinkage
• Interdendritic Shrinkage
• Gas porosity
How to prevent solidification defects?
Proper pouring temperature, mold design, feeding systems, gas removal, and controlled cooling help
Alloy
A metal made by taking a pure metal and adding another material to it
Components
The elements which make up an alloy
Composition
The elemental make up, often by weight %, volume %, etc.
Phase
any portion of a system that is physically
homogeneous and bounded by a surface that
separates it from other distinct portions
Solid Solution
is a solid material in which atoms of one element are mixed uniformly into the crystal structure of another element.
Limited Solubility
Only a certain amount of one element can dissolve in the other.
Beyond that limit, a second phase may form.
Unlimited Solubility
The two elements can dissolve in each other in any proportion in the solid state.
They form a single solid-solution phase across the entire composition range.
Hume-Rothery Rules
Size – must be similar with <15% difference in
atomic radius
• Crystal structure – must be the same
• Valence – must be the same (or close)
• Electronegativity – must be approximately the
same
Solid Solution Strengthening
Formed in metals due to increased resistance to dislocation motion
Degree of strengthening depends on two factors…
1. A large difference in atomic sizes results in
increased strength of the alloy
2. The greater the amount of the alloying element
that is added, the greater the strengthening
Solid-Solution Strengthening Effects on Properties
σY, σUTS, H of the alloy
increase compared to pure
metal
• Ductility decreases
compared to pure metal
• Electrical conductivity
decreases compared to
pure metal
• Resistance to creep and
strength at high temperatures increases
compared to pure metal.
Segregation
the nonuniform composition produced by
nonequilibrium solidification
Microsegregation
heating to below the nonequilibrium
solidus for a few hours eliminates most of the
composition differences (‘homogenization’)