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Element by itself like O_2, Fe, or Cl_2
0
Group 1 metals, like Na and K
+1
Group 2 metals, like Ca and Mg
+2
Hydrogen in most compounds
+1
Oxygen in most compounds
−2
Fluorine in compounds
−1
Single-atom ion, like Fe^3+
Equal to its charge
Neutral compound
All oxidation numbers add to 0
Polyatomic ion
All oxidation numbers add to the ion's charge
Exceptions to remember:
oxygen is −1 in peroxides such as H_2O_2, and hydrogen is −1 in metal hydrides such as NaH