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VULCANIZED RUBBER
1853; plant-derivative latex crosslinked with sulfur was
introduced as a denture base material
CELLULOID
1853; nitrocellulose material was also adapted as a
denture base material.
ELASTOMERIC POLYMER
VULCANIZED RUBBER AND CELLULOID AS DENTURE BASE MATERIAL IN 1853
Polymeros
The Greek words meaning “many” and “part” from which the word polymer is derived.
Polymer
The long-chain organic molecules made up of many repeating units.
monomers
The repeating units that make up a polymer.
homopolymer
polymer containing only one type of repeating unit.
copolymer
polymer containing two or more chemically different repeating units.
random copolymer
copolymer in which there is no sequential order among the different mer units.
block copolymer
copolymer where identical monomer units occur in relatively long sequences.
grafted or branch copolymer
copolymer where one type of mer unit is grafted onto the backbone of another type.
polymerization
process involving repetitive intermolecular chain growth.
natural polymers
polymer obtained from natural materials such as cotton, silk, wool, and natural rubber.
synthetic polymers
polymer synthesized from low-molecular-weight compounds.
organic polymers
polymer whose backbone chain is made of carbon atoms.
inorganic polymer
polymer that does not have carbon atoms in its chain.
linear polymer
Polymers whose structural units are connected in a linear sequence.
branched polymer
Polymers with side chains connected to the main chain.
cross linked polymer
Polymers in which adjacent linear chains are joined by covalent bonds.
thermoplastic resins
Resins that soften when heated and harden when cooled.
thermosetting resins
Resins that undergo a chemical change during setting and do not soften when reheated.
plastic strain
Irreversible deformation caused by slippage or flow among polymer chains.
elastic strain
Reversible deformation that is completely recovered after stress is removed.
viscoelastic strain
combination of elastic and plastic deformation where only the elastic portion is recovered.
plastic flow
in which polymer chains slide over one another, producing permanent deformation.
elastic recovery
Reversible strain where polymer chains straighten and recoil like springs.
solvation
The process in which a polymer absorbs a solvent, swells, and softens.
plasticization
The lubricating effect caused by absorbed molecules spreading polymer chains apart.