nomenclature of oc

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254 Terms

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What is IUPAC?
International Union of Pure and Applied Chemistry — the body that sets systematic naming rules
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What is a functional group?
An atom or group that determines chemical properties and class of an organic compound
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What is a homologous series?
A series of compounds with the same functional group differing by –CH₂–
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What is a principal functional group?
The highest-priority group that becomes the suffix and gets the lowest number.

What is the general formula for an IUPAC name?
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What is the Longest Chain Rule?
Choose the longest continuous carbon chain; if tie
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choose the one with most substituents
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What is the Lowest Number Rule?
Number from the end giving lowest locants to principal group
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then multiple bonds
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then substituents
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What is the Alphabetical Order Rule?
List substituents alphabetically ignoring di-
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tri-
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sec-
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tert-.

What is the Vowel Elision Rule?
Drop the terminal "e" of the primary suffix before a vowel (a
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e
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i
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o
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u)
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Is "y" a vowel in IUPAC?
No
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"y" is a consonant and does not trigger elision
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When is "e" kept?
Before consonant-starting suffixes like -nitrile and -thiol.

What is the rule for numbering double and triple bonds?
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How are -ene and -yne ordered in the name?
-ene comes before -yne
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Where does the position number go?
Immediately before -ene or -yne (e.g.
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pent-1-en-4-yne).

What is the 4-step trick for polyfunctional compounds?
Pick the King → Number the Kingdom → Crown the King → Alphabetize the Crowd
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What does each step mean?
King = highest priority group; number so King gets lowest locant; King becomes suffix; other groups become prefixes alphabetically
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What is the golden rule for acids?
–COOH always wins if present
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Which groups are never principal?
Halides
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nitro
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and ether are always prefixes.

What is the prefix and suffix for carboxylic acid?
prefix carboxy-
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suffix -oic acid
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What is the prefix and suffix for sulphonic acid?
prefix sulpho-
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suffix -sulphonic acid
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What is the prefix and suffix for ester?
prefix alkoxycarbonyl-
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suffix -oate
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What is the prefix and suffix for acid halide?
prefix haloformyl-
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suffix -oyl halide
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What is the prefix and suffix for amide?
prefix carbamoyl-
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suffix -amide
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What is the prefix and suffix for nitrile?
prefix cyano-
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suffix -nitrile
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What is the prefix and suffix for aldehyde?
prefix formyl-/oxo-
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suffix -al
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What is the prefix and suffix for ketone?
prefix oxo-
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suffix -one
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What is the prefix and suffix for alcohol?
prefix hydroxy-
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suffix -ol
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What is the prefix and suffix for thiol?
prefix mercapto-
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suffix -thiol
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What is the prefix and suffix for amine?
prefix amino-
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suffix -amine
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What is the suffix for alkene?
-ene
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What is the suffix for alkyne?
-yne
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What is the prefix for halide?
fluoro-/chloro-/bromo-/iodo- (always prefix)
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What is the prefix for nitro?
nitro- (always prefix)
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What is the prefix for ether?
alkoxy- (always prefix).

What is the priority order of functional groups?
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What is the mnemonic?
"Can Sita Eat All Apples? No! Anil Keeps All Ten Apples At Aunt's House."

What is the general formula for alkane?
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What is the general formula for alkene?
CₙH₂ₙ
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What is the general formula for alkyne?
CₙH₂ₙ₋₂
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What is the general formula for alcohol/ether?
CₙH₂ₙ₊₂O
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What is the general formula for aldehyde/ketone?
CₙH₂ₙO
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What is the general formula for carboxylic acid/ester?
CₙH₂ₙO₂
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What is the general formula for amine?
CₙH₂ₙ₊₃N.

What is the common name and formula for methane?
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CH₄
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What is the common name and formula for ethane?
ethane
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C₂H₆
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What is the common name and formula for propane?
propane
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C₃H₈
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What is the common name and formula for butane?
n-butane
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C₄H₁₀
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What is the common name and formula for isobutane?
2-methylpropane
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C₄H₁₀
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What is the common name and formula for ethene?
ethylene
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C₂H₄
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What is the common name and formula for ethyne?
acetylene
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C₂H₂
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What is the common name and formula for methanol?
wood spirit
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CH₃OH
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What is the common name and formula for ethanol?
grain alcohol
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C₂H₅OH
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What is the common name and formula for methanal?
formaldehyde
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HCHO
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What is the common name and formula for ethanal?
acetaldehyde
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CH₃CHO
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What is the common name and formula for propanone?
acetone
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CH₃COCH₃
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What is the common name and formula for methanoic acid?
formic acid
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HCOOH
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What is the common name and formula for ethanoic acid?
acetic acid
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CH₃COOH
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What is the common name and formula for methoxymethane?
dimethyl ether
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CH₃OCH₃
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What is the common name and formula for ethoxyethane?
diethyl ether
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C₂H₅OC₂H₅
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What is the common name and formula for methyl ethanoate?
methyl acetate
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CH₃COOCH₃
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What is the common name and formula for methanamine?
methylamine
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CH₃NH₂
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What is the common name and formula for chloromethane?
methyl chloride
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CH₃Cl
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What is the common name and formula for bromoethane?
ethyl bromide
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C₂H₅Br.

What is nail polish remover chemically?
Acetone-based = propanone (CH₃COCH₃