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What is sustainability?
Using resources at a rate that lets them be replenished, meeting present needs without compromising future generations' ability to meet theirs.
What is maximum sustainable yield (MSY)?
The largest amount of a renewable resource (fish, timber) that can be harvested each year without reducing its ability to renew itself long term.
What is the Tragedy of the Commons?
When individuals acting in self-interest overuse a shared, open-access resource (pasture, fishery, air, water), depleting it for everyone.
How do we address the Tragedy of the Commons?
Regulations and quotas, permits and fees, privatization or community management, education, international agreements, enforcement.
What is an ecological footprint?
The total land and water area needed to produce the resources a person or population consumes and to absorb the waste it produces.
How can we reduce our ecological footprint?
Eat less meat and eat local, use public transit/bike/EVs, conserve energy and water, use renewable energy, reduce-reuse-recycle, buy less, use efficient appliances.
Small energy conservation steps at home?
LED bulbs, unplug electronics, adjust thermostat, seal drafts, cold-water laundry, line-dry clothes, Energy Star appliances, shorter showers.
Larger energy conservation techniques?
Insulation and weatherization, double-pane windows, solar panels, heat pumps, green building design, hybrid/electric vehicles, public transit, smart grids, cogeneration, CAFE standards.
Renewable resource
Replenished naturally on a human timescale (solar, wind, hydro, geothermal, biomass, tidal).
Nonrenewable resource
Finite or forms over millions of years (coal, oil, natural gas, uranium).
3 main countries that have oil
Venezuela, Saudi Arabia, Canada (also Iran, Iraq).
3 main countries that use oil
United States, China, India.
3 main countries that have natural gas
Russia, Iran, Qatar.
3 main countries that use natural gas
United States, Russia, China.
3 main countries that have coal
United States, Russia, Australia (also China, India).
3 main countries that use coal
China, India, United States.
As a country becomes more industrialized, its energy use and dependence ______.
Increases.
Wood as a fuel
Burned for heating and cooking (biomass); main fuel in many developing regions.
Peat as a fuel
Partially decomposed plant matter from bogs; burned for heat and electricity (Ireland, Finland, Russia); low energy content, high CO2.
Lignite
Lowest-rank coal: lowest carbon and energy content.
Bituminous coal
Most common coal; mid-range energy; used for electricity and steel.
Anthracite
Highest-rank coal: highest carbon and energy, cleanest burning.
Natural gas as a fuel
Mostly methane; used for heating, cooking, electricity; cleanest fossil fuel.
Crude oil as a fuel
Refined by fractional distillation into gasoline, diesel, jet fuel, heating oil, asphalt, plastics and petrochemicals.
What is cogeneration (CHP)?
Using waste heat from electricity generation for heating or industrial processes.
Benefits of cogeneration
Efficiency of about 70-90% vs about 35-40% for electricity alone; less fuel burned; lower emissions and costs.
Combustion reaction formula
CxHx + O2 -> CO2 + H2O (+ energy)
How do fossil fuels make electricity?
Burn fuel -> heat boils water -> steam spins a turbine -> turbine spins a generator -> electricity. Steam is condensed and reused.
Fossil fuel extraction techniques
Surface mining (strip, open-pit, mountaintop removal), subsurface mining, conventional and offshore drilling, tar/oil sands, hydraulic fracturing.
What is fracking?
Injecting high-pressure water, sand, and chemicals into shale to fracture rock and release trapped gas or oil.
Side effects of fracking
Groundwater contamination, huge water use, wastewater disposal, methane leaks, induced earthquakes, habitat disruption.
Main pollutants from coal combustion
CO2, SO2, NOx, particulates (fly ash), mercury and other heavy metals, CO.
Pollutants from all fossil fuel burning
CO2, CO, NOx, VOCs/unburned hydrocarbons, particulates, SO2 (mainly coal and oil).
SPLONC: what does it stand for?
Sulfur dioxide, Particulates, Lead, Ozone, Nitrogen oxides, Carbon monoxide (pollutants regulated by the Clean Air Act and EPA).
Which SPLONC pollutant has been reduced most successfully?
Lead (leaded gasoline and paint were phased out).
Primary pollutant
Emitted directly from a source (CO, CO2, SO2, NOx, VOCs, particulates, lead).
Secondary pollutant
Forms in the atmosphere when primary pollutants react (ozone, PAN, sulfuric acid, nitric acid, photochemical smog).
Carbon monoxide (indoor): what, source, effect
Colorless, odorless gas from incomplete combustion (furnaces, gas stoves, fireplaces, car exhaust). Binds hemoglobin instead of oxygen: headaches, dizziness, death.
Asbestos
Old insulation, tiles, building materials. Causes asbestosis, lung cancer, mesothelioma.
Indoor smoke
From tobacco, fireplaces, wood stoves. Causes respiratory disease, asthma, lung cancer.
Indoor dust
Skin, pollen, dust mites, pet dander. Causes allergies and asthma.
Radon
Radioactive gas from uranium decay in rock/soil; seeps through foundations and basements. #2 cause of lung cancer.
Mold
Grows in damp, humid areas. Causes allergies, asthma, respiratory irritation.
VOCs (indoor)
From paints, cleaners, furniture, carpet, air fresheners. Cause headaches, eye/throat irritation, organ damage, some cancers.
Formaldehyde
From pressed wood, glues, insulation, new furniture. Causes eye/respiratory irritation and cancer.
Lead (indoor)
From old paint and pipes. Causes nervous system damage, especially in children.
Major components of Earth's atmosphere
Nitrogen ~78%, oxygen ~21%, argon ~0.9%, CO2 ~0.04%, water vapor 0-4% (variable).
Troposphere
0 to ~12 km; where we live and weather happens; most of the air's mass; temperature drops with height.
Stratosphere
~12 to 50 km; contains the ozone layer, which absorbs UV; temperature rises with height.
Mesosphere
~50 to 85 km; coldest layer; meteors burn up.
Thermosphere
~85 to 600 km; very hot, thin air; auroras; satellites and the ISS.
Where is oil found?
Middle East (Saudi Arabia, Iran, Iraq), Venezuela, Canada, Russia, United States.
Where is natural gas found?
Russia, Iran, Qatar, United States.
Where is coal found?
United States, Russia, China, Australia, India.
Where are key minerals found?
Lithium (Australia, Chile), cobalt (DR Congo), copper (Chile), platinum (South Africa), bauxite (Australia, Guinea), rare earths (China), iron ore (Australia, Brazil).
What causes photochemical smog?
Sunlight reacting with nitrogen oxides (NOx) and VOCs, forming ground-level ozone and PAN.
Chemical reactions of photochemical smog
N2 + O2 -> 2NO (engine heat); 2NO + O2 -> 2NO2; NO2 + sunlight -> NO + O; O + O2 -> O3; NOx + VOCs + sunlight -> ozone + PAN.
When is NOx highest during the day?
Morning rush hour (~6-9 a.m.).
When is ozone highest and why?
Afternoon (~noon-4 p.m.) because it needs strong sunlight and NO2 that built up in the morning.
Sources of VOCs
Natural: trees (isoprene, terpenes), wetlands, vegetation. Artificial: gasoline vapors, paints, solvents, cleaning products, industry.
Why is smog more common in urban areas?
More cars and industry (NOx and VOCs), dense development, heat islands, and geography that can trap air.
How to reduce photochemical smog
Catalytic converters, vapor recovery nozzles, public transit/EVs, low-VOC products, emissions standards, driving less on hot days, cleaner power plants.
How is photochemical smog harmful to humans?
Eye, nose, throat irritation; asthma attacks; reduced lung function; lung damage. Also damages crops, plants, and rubber.
How does a thermal inversion work?
A layer of warm air sits above cooler air near the ground, acting like a lid that stops the cool air from rising.
Why are thermal inversions problematic?
Pollutants are trapped near the surface and concentrate, intensifying smog and causing respiratory problems.
Example cities with thermal inversions
Los Angeles, Mexico City, Denver, Salt Lake City, Beijing (valleys/basins ringed by mountains).
Natural sources of CO2
Respiration, decomposition, volcanoes, wildfires, ocean outgassing.
Anthropogenic sources of CO2
Burning fossil fuels, deforestation, cement production, agriculture.
Natural sources of particulates
Volcanic ash, dust storms, wildfires, sea spray, pollen.
Anthropogenic sources of particulates
Coal burning, diesel exhaust, construction, agricultural tilling, burning biomass.
Reducing air pollutants: Reduce
Use less energy, drive less, buy less.
Reducing air pollutants: Conservation
Improve efficiency (insulation, efficient appliances and vehicles).
Reducing air pollutants: Alternative fuels
Solar, wind, hydro, hydrogen, biofuels, natural gas.
What do vapor recovery nozzles do?
Capture gasoline vapors (VOCs) during refueling so they do not escape into the air.
What does a catalytic converter do?
Uses catalysts (platinum, palladium, rhodium) in car exhaust to convert harmful gases into less harmful ones.
Catalytic converter: what it converts
CO, NOx, and unburned hydrocarbons.
Catalytic converter: what they become
CO2, N2, H2O (and O2).
What do wet and dry scrubbers do?
Remove pollutants from smokestack gas. Wet: spray water or limestone slurry. Dry: inject dry sorbent (lime) that reacts with the gas.
What pollutants do scrubbers remove?
SO2 (also some acid gases and particulates).
What do electrostatic precipitators do?
Give particles an electric charge, then collect them on oppositely charged plates.
What pollutants do electrostatic precipitators remove?
Particulates (ash, soot, dust).
What chemicals cause acid rain?
Sulfur dioxide (SO2) and nitrogen oxides (NOx).
Sources of acid rain chemicals
Natural: volcanoes, lightning, wildfires, decomposition. Man-made: coal power plants, vehicles, industry, smelting.
Main acid rain formulas
SO2 + H2O -> H2SO3 (or SO3 + H2O -> H2SO4, sulfuric acid); NO2 + H2O -> HNO3 (nitric acid).
Environmental effects of acid rain
Acidifies lakes and streams (pH below 5 kills fish and amphibian eggs), leaches soil nutrients (Ca, Mg) and frees toxic aluminum, damages forests, corrodes buildings, statues, and metal.
How do soil types affect acid rain potency?
Limestone or alkaline soils buffer acid; thin, granite-based soils have little buffering, so ecosystems are hit harder.
What can neutralize acid rain?
Bases such as limestone (calcium carbonate) or lime added to lakes and soil (liming).
Long-term solution for acid rain
Cut SO2 and NOx emissions: scrubbers, renewable energy, burning less coal, catalytic converters, cap-and-trade.
What is solid waste?
Any discarded solid material from homes, businesses, industry, and agriculture (municipal solid waste = household and commercial trash).
Three ways we dispose of waste
Landfilling, incineration, ocean dumping (plus recycling and composting as diversion).
What is e-waste and what are the concerns?
Discarded electronics. Toxic heavy metals (lead, mercury, cadmium) leach into soil and water; often exported and dismantled unsafely.
Problems with landfills
Leachate contaminating groundwater, methane and odors, running out of space, land use, pests, slow decomposition.
What is a sanitary landfill?
An engineered landfill where waste is compacted and covered with soil daily, with liners and systems to control leachate and gas.
Important layers/components of a sanitary landfill
Clay and plastic liner, leachate collection system, daily soil cover, methane collection pipes, final cap (clay and soil), groundwater monitoring wells.
How does waste break down in a landfill?
Mostly anaerobic decomposition (little oxygen), which is very slow and produces methane.
What is not allowed in a sanitary landfill?
Hazardous waste (paint, solvents, pesticides), batteries, electronics, liquids, and often tires and yard waste.
What helps landfill waste break down?
Moisture and oxygen, shredding waste, less compaction (bioreactor landfills).
How are banned landfill items disposed of?
Hazardous waste collection events or facilities, special e-waste/battery recycling, take-back programs.
How does incineration work?
Burning waste at high temperature, reducing volume by ~90%; heat can generate electricity (waste-to-energy).
Drawbacks of incineration
Air pollution (dioxins, heavy metals, particulates), toxic ash, high cost, discourages recycling.