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Carboxylic Group
Posses at least one -COOH group, sometimes more
•They are true acids because they dissociate in water forming a conjugate base and a
hydronium ion (A hydronium ion is a positively charged ion (a cation) with the chemical
formula 3 +. Hydronium ions are crucial in aqueous solutions for determining a𝐻 𝑂
solution's acidity; a higher concentration of hydronium ions indicates a lower pH value,
meaning the solution is more acidic)
weak acids
the only acidic hydrogen is the one
attached to the oxygen atom
Naming Carboxylic Acids
Named as derivatives of alkanes
•Also known by common names associated with their source of isolatio
Organic acids are sometimes referred to as _______ because they naturally occur in fats
fatty acids
Salts of Carboxylic Acids
In the presence of a strong base, such as sodium hydroxide, carboxylic acids are completely neutralized
Salts of Carboxylic Acids are named by
naming the metal followed by changing the -ic acid of the
carboxylic acid to -ate
Famous Sodium Carboxylates
- acts as corrosion inhibitors, anticoagulants,
and water conditioners, sodium formate, sodium acetate, sodium benzoate
(Sodium Formate)
Food additive/preservative
(Sodium acetate)
Seasoning added to potato chips
(Sodium benzoate)
Preservative in salad dressings, carbonated drinks, relish, and pickles. Also used as a preservative in medicine and cosmetics
Poly carboxylic acids contain
two or more carboxylic groups
The simplest dicarboxylic acid is
oxalic acid
dicarboxylic acid is used as a
anticoagulant and water softner
Oxalic acids can be converted into a ____ (sodium oxalate) salt by adding a strong base
disodium
was the first water softener and anticoagulant used in the
funeral service industr
disodium salt
When soluble sodium oxalate is the modifying agent in your embalming fluid,_________ out of solution when added to hard wat
calcium oxalate precipitates
Acetic acid (commonly known as vinegar)
reacts with hard water deposits like calcium ion creating the water soluble compound calcium acetae
Tricarboxylic acids
used as sequestrant anticoagulants
(sequester: to hold) prevent blood from clotting by binding to
and removing calcium ions from the blood
Potassium citrate
does not remove Ca+2 ions, cages (sequesters) them in and prevents them from coagulating and clotting
blood during embalming procedur
EDTA (Ethylenediaminetetraacetat)
used as buffer, Colorless, water soluble, polycarboxylic acid, Chelating Sequesterant anticoagulant
chelating agent
a chemical compound that binds tightly to metal ions, forming a ring-
like structure called chelate
Esters
•Formed by reaction of a carboxylic acid with an alcohol, ex triglycerides, trigger pheremones response in some animals and insects
Methyl Salicylate
•This is the star fragrance for the embalmer- used as a deodorant in embalming
Ester group creates a
wintergreen scent
thioesters
First cousin to the ester, bad odor, No role in embalming fluid but very important biologically
•Acetyl Coenzyme-A (or acetyl-CoA) is an important thioester in metabolis