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intramolecular bonds
bonds within molecules
intramolecular bond types
ionic, covalent, metallic
intermolecular bonds
bonds between molecules
intermolecular bond types
van der Waal's (London dispersion), dipole-dipole, ion-dipole, hydrogen bonding
van der Waal's (London dispersion)
a slight attraction that develops between the oppositely charged regions of nearby molecules
dipole-dipole
attractions between oppositely charged regions of polar molecules
ion-dipole
the charge of an ion is attracted to the partial charge on a polar molecule
hydrogen bonding
the intermolecular force in which a hydrogen atom that is bonded to a highly electronegative atom is attracted to an unshared pair of electrons of an electronegative atom in a nearby molecule
crystalline solids
highly organized lattice structures; definite melting point
polymorphic crystalline solids
same material can havedifferent lattice arrangementsand therefore differentphysical properties
amorphous solids
irregular structures; no clear melting point
polymeric solids
repetition of a basic structure
eutectic point
two solids interact to depress each other's melting points
danger for inter-conversion
some polymeric forms are more stable than others
poor solubility
generally poor bio-availability to the patient
salts
ionic compounds made from the neutralization of an acid with a base
heteromeric crystals
have other types of molecules (e.g. water or
counter ions) accommodated in the crystal lattice
hydrate
compound that has water chemically attached to its ions and written into its chemical formula
solvate
a compound formed by solvation (the combination of solvent molecules with molecules or ions of the solute)