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a lot of unit 3
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what is chirality?
object or molecule that cannot be superimposed on to its mirror image
What factor of water is the major determinant for its cohesiveness and surface tension?
hydrogen bonds
self assembly principle that specify folding and biological functions of macromolecules
encoded in polymers
Most proteins in nature are found in this stereoisomeric form
L form
Which amino acid doesn’t have chiral carbon?
glycine
Another name for strong covalent bond formed by oxidation between 2 cysteine side chains
disulfide linkage/bond
Which 2 adjacent amino acids are joined in formation of peptide bond?
carboxyl group of 1st AA and amino group of 2nd
primary structure of protein is stablized exclusively by this bond
peptide bond
first protein to have complete amino acid sequence determined
insulin
In alpha helix, H bonds stabilize secondary structure by connecting CO group of n residue with CO group of which other residue?
n+4
Type of secondary structure described as being extended, resisting pulling, and exhibiting more tensile strength
beta-pleated sheets
Distinction between motif and domain
domain is larger with specific function, motif is smaller, local folding pattern w/out function
Tertiary protein structure primarily result of interactions between R groups including non-covalent bonds except
phosphodiester
Monomers in DNA and RNA linked together by this bond
phosphodiester bond
How do DNA specimens isolated from different tissues within the same species compare?
they have same base composition
nucleoside is combination of
sugar and base
Carbs generally desc as polyhydroxy aldehydes and ketones and have this empirical formula
(CH2O)n
Monosaccharides with more than 5 carbons in backbone exist in this form primarily
Cyclic form
polysaccharides that function in energy storage for animal cells are called glycogen. What characteristic linkages do they feature?
highly branched structures with alpha 1-6 linkage in every 8 to 10 glucose units
Chitin has which modified sugar unit
N-acetylglucosamine units
Which characteristic of lipids links them together chemically, unlike other macromolecules
they are hydrophobic
Lipids considered macromolecules because of their
high molecular weight and importance in cellular structures
saturated fatty acid has
NO double bonds
Triglycerides form when 3 fatty acids bond to glycerol with this type of reaction
condensation reaction that forms ester bonds
triglycerides composed mostly of unsaturated fatty acids tend to exist in this state at room temp
liquid
phospholipids are amphipathic bc they have
both hydrophobic and hydrophilic regions
structure of steroid defined chemically by derivative of this specific ring compound
phenanthrene
only property that links steroids to other lipids
hydrophobicity
This specific steroid is considered as important component to most cell membranes and is produced in almost 90% by cells in our liver
cholesterol
Terpenes synthesized from this 5-carbon sugar unit
isoprene
Besides forming Vit. A or carotenoids, polyisoprenes are also components of the membrane in this domain of life
archaea